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Figure 4. a) Binding geometries and energies of a Li2S4 molecule on graphene (left) and the (111) plane of CoS2 with a cobalt-terminated surface (right). b) A schematic illustration of the discharge process in CoS2-incorporated carbon/sulfur cathode. c) Schematic illustration of the synthesis process for Co9S8/C-S nanopolyhedra. d) Calculated adsorption energies (Ea) of S8 and Li2Sx (x = 1, 2, 4, 6, or 8) species on (202) planes of Co9S8 crystals. e) Adsorption capability comparison of activated carbon (left vial) and Co9S8/C hollow nanopolyhedra (right vial) within a solution of Li2S4 as a representative polysulfide (in mixed dioxolane (DOL)/dimethoxyethane (DME) solvent). a,b) Reproduced with permission. [70] Copyright 2016, American Chemical Society. c-e) Reproduced with permission.[71] Copyright 2017, Elsevier. 31PDF Image | Advances in Polar Materials for Lithium-Sulfur Batteries
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