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Figure 5. a) Schematic diagram of the synthesis process for Li2S@TiS2 core-shell nanostructures. b) Ab initio simulations showing the most stable binding configuration of Li2S with a single layer of (left) TiS2, (middle) ZrS2, and (right) VS2, with calculated binding energies of 2.99, 2.70, and 2.94 eV, respectively. c) Cycling performance of Li2S@TiS2 and bare Li2S cathodes at 0.2 C (left) and charge–discharge voltage profiles of Li2S@TiS2 cathodes cycled from 0.2 to 4 C (right). a-c) Reproduced with permission. [72] Copyright 2014, Nature Publishing Group. 32PDF Image | Advances in Polar Materials for Lithium-Sulfur Batteries
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