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Figure 6. a) Geometry optimization of the interaction between Ti atoms on the surface of Ti2C and sulfur species. (b) Ti 2p XPS spectrum (left) of i) Ti2C nanosheets, ii) S/Ti2C composite, iii) Li2S4 -Ti2C, and iv) 70S/Ti2C electrodes discharged to 1.8 V; S 2p XPS spectra (right) of i) elemental sulfur, ii) 70S/Ti2C composite, and iii) 70S/Ti2C electrode discharged to 1.8 V. c) Illustration of the working mechanism of the polar conductor as it meets the demand for both adequate binding and charge transfer. d) The binding energies of TiC to Li2S4 and Li2S compared to pristine graphene. a,b) Reproduced with permission. [85] Copyright 2015, Wiley- VCH. c,d) Reproduced with permission.[87] Copyright 2016, Wiley-VCH. 33PDF Image | Advances in Polar Materials for Lithium-Sulfur Batteries
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