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HANDBOOK ON THE PHYSICS AND CHEMISTRY OF RARE EARTHS

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HANDBOOK ON THE PHYSICS AND CHEMISTRY OF RARE EARTHS ( handbook-onphysics-and-chemistry-rare-earths )

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26 Handbook on the Physics and Chemistry of Rare Earths ex. 1 0.5 0 em 300 400 Wavelength (nm) Excitation and emission spectra of Li2SrSiO4:Eu2+. Redrawn from Toda, K., Kawakami, Y., Kousaka, S., Ito, Y., Komeno, A., Uematsu, K., Sato, M., 2006. New silicate phosphors for a white LED. IEICE Trans. Electron. E89-C, 1406–1412. 100 80 60 40 20 0 50 100 150 200 Temperature (°C) Temperature dependence of the emission intensity of Li2SrSiO4:Eu2+ phosphor. Redrawn from Toda, K., Kawakami, Y., Kousaka, S., Ito, Y., Komeno, A., Uematsu, K., Sato, M., 2006. New silicate phosphors for a white LED. IEICE Trans. Electron. E89-C, 1406–1412. 4.1.1.5 Ba3Sc4O9:Ce3+ Phosphors Hasegawa et al. (2014) recently reported novel yellow-emitting Ce3+- activated phosphors based on Ba3Sc4O9 which crystallizes in a trigonal struc- ture with space group R3 (Spitsyn et al., 1968) (Fig. 20). The structure is built up of BaOn (n1⁄49 and 12) polyhedra and ScO6 octahedra forming FIG. 18 500 600 700 FIG. 19 Relative intensity (%) Normalized intensity (a.u.)

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