HANDBOOK ON THE PHYSICS AND CHEMISTRY OF RARE EARTHS

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HANDBOOK ON THE PHYSICS AND CHEMISTRY OF RARE EARTHS ( handbook-onphysics-and-chemistry-rare-earths )

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32 Handbook on the Physics and Chemistry of Rare Earths Simulation pattern from single crystal analysis Powder Ba2MgSi2O7:Eu2+ 10 20 30 40 50 60 70 2q (°) XRD patterns of powder and single crystal Ba2MgSi2O7:Eu2+. Redrawn from Toda, K., Kawakami, Y., Kousaka, S., Ito, Y., Komeno, A., Uematsu, K., Sato, M., 2006. New silicate phosphors for a white LED. IEICE Trans. Electron. E89-C, 1406–1412; Komeno, A., Uematsu, K., Toda, K., Sato, M., 2006. VUV properties of Eu-doped alkaline earth magnesium silicate. J. Alloy Compd. 408–412, 871–874. FIG. 27 Pattern fitting of the powder neutron diffraction of Ba2MgSi2O7:Eu2+. Redrawn from Toda, K., Kawakami, Y., Kousaka, S., Ito, Y., Komeno, A., Uematsu, K., Sato, M., 2006. New silicate phosphors for a white LED. IEICE Trans. Electron. E89-C, 1406–1412; Komeno, A., Uematsu, K., Toda, K., Sato, M., 2006. VUV properties of Eu-doped alkaline earth magnesium silicate. J. Alloy Compd. 408–412, 871–874. pattern fitting figure calculated from the Rietveld refinement of powder neu- tron diffraction data of Ba2MgSi2O7 is shown in Fig. 27, and the refined crystallographic data are summarized in Table 1. Indexing of the XRD patterns of Ba2MgSi2O7:Eu2+ certainly indicates a monoclinic symmetry with space group C2/c, a1⁄40.8426 nm, b1⁄41.0726 nm, c1⁄40.8449 nm, and FIG. 26 Intensity (a. u.)

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