HANDBOOK ON THE PHYSICS AND CHEMISTRY OF RARE EARTHS

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HANDBOOK ON THE PHYSICS AND CHEMISTRY OF RARE EARTHS ( handbook-onphysics-and-chemistry-rare-earths )

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REE Mineralogy and Resources Chapter 279 137 where C is concentration, subscript i refers to an element and superscripts a and b refer to a- and b-phases, respectively. The partitioning coefficients are related to the pressure, temperature, chemical composition, and oxygen fugacity of the melts or fluids. These coefficients have been estimated by numerous experiments, chemical analyses of natural materials, and theoretical calculations. Although the partitioning coefficients of the REEs are affected by various factors mentioned earlier, it is useful to compare the coefficients of representa- tive minerals in the igneous rocks (for example, basalt) for understanding of the behavior of the REEs. White (2013) compiled the mineral–melt partition coefficients of REEs for mafic magmas, based on the data assembled in Geo- chemical Earth Reference Model (GERM, www.earthref.org/GERM; Fig. 3). These results show that the coefficients of clinopyroxene, garnet, plagioclase, and amphibole are much higher than those of olivine and spinel, and the minerals with the high partitioning coefficients control the concentration of REEs. Although olivine is the most abundant mineral in the upper mantle, the partitioning of REEs is not significantly affected because of its low coefficients. Among REEs, europium is highly partitioned to plagioclase because diva- lent (Eu2+) europium in relatively reducing conditions substitutes for Ca2+ in 101 10−0 10−1 10−2 10−3 10−4 10−5 Clinopyroxene Amphibole Plagioclase Spinel FIG. 3 10−6 REE mineral-melt partition coefficients for mafic magmas after White (2013). La Ce Pr Nd Sm Eu Gd Tb Dy Ho Er Tm Yb Lu Garnet Mineral–melt partition coefficient Or thopyroxene Olivine

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