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HANDBOOK ON THE PHYSICS AND CHEMISTRY OF RARE EARTHS

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HANDBOOK ON THE PHYSICS AND CHEMISTRY OF RARE EARTHS ( handbook-onphysics-and-chemistry-rare-earths )

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184 Handbook on the Physics and Chemistry of Rare Earths FIG. 25 Plot of Ca vs Mn of the allanite-(Ce) samples, suggesting substitution of Mn for Ca. The dashed line shows the boundary between Mn-rich and Mn-poor allanite-(Ce), at 0.14 apfu Mn (Broska et al., 2000; Claeson, 2002; Hoshino et al., 2006; Catlos et al., 2000; Kartashov et al., 2002; Miyawaki et al., 2008; Oberli et al., 2004; Peterson and MacFarlane, 1993; Smith et al., 2002; Wood and Ricketts, 2000). This plot was modified from Hoshino, M., Kimata, M., Shimizu, M., Nishida, N., Fujiwara, T., 2006. Allanite-(Ce) in granitic rocks from Japan: genetic implications of patterns of REE and Mn enrichment. Can. Mineral. 44, 45–62. Van Lichtervelde et al., 2009) is highly variable, while zircon from Japanese granitic rocks has a wide range of Y content. Although hafnian zircons (HfO2>10wt.%) from many granitic pegmatite occur in the intracontinental settings, zircons from the granitic rocks in the Japanese arc always have HfO2 content less than 10 wt.% (Fig. 27). In subduction-related volcanic rocks, HFSE (Nb, Ta, Zr, and Hf ) display a characteristic depletion relative to REEs and large-ion lihophile elements (LILE) (Pearce and Peate, 1995). The average global subducted sediment is enriched in Ba, Mn, and HREEs relative to upper continental crust (Plank and Langmuir, 1998). Therefore, occurrence of Y-rich and Hf-poor zircon may be related to the above subduction magmatism, namely the Japanese island arc. Hoshino et al. (2012b) reported that monazite from magnetite-series granitic rocks is relatively rich in LREEs, whereas monazite in ilmenite-series granitic rocks exhibits enrichment in MREEs, which is similar to geochemical behavior for allanite from Japanese granitic rocks (Fig. 26). As already mentioned, mon- azite is isostructural with huttonite and cheralite, so they display variable solid

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