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HIGH STRENGTH CARBON NANOFIBERS DERIVED FROM ELECTROSPUN POLYACRYLONITRILE

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HIGH STRENGTH CARBON NANOFIBERS DERIVED FROM ELECTROSPUN POLYACRYLONITRILE ( high-strength-carbon-nanofibers-derived-from-electrospun-pol )

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Prior literature has emphasized the detrimental core-shell structure of PAN-based carbon nanofibers, which, as shown in Figure 3.5(b), was not present in the present carbon nanofibers. On the other hand, the TEM images of carbon nanofibers in Figures 3.6(a-d) showed randomly oriented turbostratic carbon crystallites whose size increased with the carbonization temperature and affected the mechanical properties dramatically, as discussed in the next section. (a) (b) (c) (d) Figure 3.6. TEM images of carbon nanofibers carbonized at (a) 800°C, (b) 1100°C, (c) 1400°C and (d) 1700°C showing the increasing size of turbostratic carbon crystallites. 29

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