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Lithium-Sulfur Battery: Design, Characterization, and Physically-based Modeling

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Lithium-Sulfur Battery: Design, Characterization, and Physically-based Modeling ( lithium-sulfur-battery-design-characterization-and-physicall )

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Today 160 km 50km 80km 100km > 550 km > 400 km > 225 km > 200 km 1000 800 600 400 200 0 Price (USD·kWh−1) PB-acid Ni-Cd Ni-MH Li-ion Future Zn-air Li-S Li-air Li-ion 200 600 900 600 < 150 < 150 < 150 < 150 Available Under development R&D Figure 1.1: Energy density of various battery chemistries compared. The lighter re- gions of the bars show the range of anticipated practical energy densities. Reproduced from [14]. New chemistries are not invented out of the blue, though. From a theoretical point of view, the properties of many potential future battery systems are well known, in- cluding those of Li/S. The challenge is to exploit this potential without compromising security, reliability, or durability known from established materials [15, 16]. In Ger- many, two national goals were formulated that cannot be achieved without significant investments in battery development, production, and deployment: the “energy revo- lution” and the advent of electromobility. Regarding the former, 80 % of Germany’s total electrical energy (and 60 % of the total gross domestic energy consumption) shall be supplied by renewables no later than 2050 [17, pp. 4f]; regarding the latter, one mil- lion electric cars shall be deployed by 2020 [18, 19]. Several national research programs support these goals [19–23] and some noteworthy results have already been obtained [23, 24]. In the U.S., national goals include 25 % of electricity consumed to be generated by cost-competitive solar and wind power by 2025 as well as one million all-electric or plug-in hybrid electric vehicles on the road by the same time [25]. Founded in 2012, the JCESR [26] is funding and conducting research to meet these targets. Also, there are dozens of ARPA-E1 projects dedicated to the development of advanced batteries. Similar programs exist in many industrialized and developing countries worldwide. Finally, there are several high-stake industrial ventures such as the USABC [27] or KLIB [28] which support research and development of next-generation batteries as part of their mission. 1Advanced Research Projects Agency-Energy, U.S. Department of Energy, 1000 Independence Ave. SW, Washington, DC 20585, USA 12 Specific energy (Wh·kg−1)

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