Supercritical Fluid Deposition Of Thin Metal Films

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titania crystals. ZnEO is used in the PRESS system to deposit highly porous dendritic zinc oxide nanostructure consisting of columnar assemblies of agglomerated zinc oxide particles of approximately 100 nm in size. These high surface area films are the first step towards making high efficiency inorganic solar cells that will be cost effective and have short fabrication times. 5.6 (1) (2) (3) (4) (5) (6) (7) (8) References S. J. J. Thompson, Philosophical Magazine 1897, 44, 293. C. Garzella, E. Comini, E. Tempesti, C. Frigeri, G. Sberveglieri, Sensors and Actuators B-Chemical 2000, 68, 189-196. I. D. Kim, A. Rothschild, B. H. Lee, D. Y. Kim, S. M. Jo, H. L. Tuller, Nano Letters 2006, 6, 2009-2013. A. M. Ruiz, G. Sakai, A. Cornet, K. Shimanoe, J. R. Morante, N. Yamazoe, Sensors and Actuators B-Chemical 2003, 93, 509-518. A. Fujishima, K. Honda, Nature 1972, 238, 37. S. N. Frank, A. J. Bard, Journal of the American Chemical Society 1977, 99, 303- 304. A. Werner, A. Roos, Solar Energy Materials and Solar Cells 2007, 91, 609-615. Y. J. Liu, R. O. Claus, Journal of the American Chemical Society 1997, 119, 5273- 5274. (9) (10) C. J. Barbe, F. Arendse, P. Comte, M. Jirousek, F. Lenzmann, V. Shklover, M. N. D. Abazovic, M. I. Comor, M. D. Dramicanin, D. J. Jovanovic, S. P. Ahrenkiel, J. M. Nedeljkovic, Journal of Physical Chemistry B 2006, 110, 25366-25370. Gratzel, J. Am. Chem. Soc. 1997, 80, 3157-3171. (11) M. Gratzel, Nature 2001, 414, 338-344. (12) M. K. Nazeeruddin, A. Kay, I. Rodicio, R. Humphry-Baker, E. Muller, P. Liska, N. Vlachopoulos, M. Gratzel, J. Am. Chem. Soc. 1993, 115, 6382-6390. 167

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