Supercritical Fluid Gaseous and Liquid States

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Entropy 2020, 22, 437 26 of 26 51. 52. 53. 54. 55. 56. 57. 58. 59. 60. 61. 62. 63. 64. 65. 66. 67. 68. 69. Gilgen, R.; Kleinrahm, R.; Wagner, W. Measurement and correlation of the (pressure, density, temperature) relation of argon. II Saturated-liquid and saturated vapour densities and vapour pressures along the entire coexistence curve. J. Chem. Thermodyn. 1994, 26, 399–413. [CrossRef] Hoover, W.G.; Poirier, J.C. Determination of virial coefficients from potential of mean force. J. Chem. Phys. 1962, 37, 1041–1042. [CrossRef] Woodcock, L.V. Thermodynamics of gas-liquid criticality: Rigidity symmetry on Gibbs density surface. Int. J. Thermophys. 2016, 37, 24–33. [CrossRef] Woodcock, L.V. Gibbs Density Surface of Water and Steam: 2nd Debate on the Absence of Van Der Waals’ “Critical Point”. Nat. Sci. 2014, 6, 411–432. [CrossRef] Sengers, J.V.; Anisimov, M.A. Comment on Gibbs Density Surface of Fluid Argon, L.V.; Woodcock, Int. J. Thermophys. (2014) 35:1770–1784. Int. J. Thermophys. 2015, 36, 3001. [CrossRef] Voronel, A.V.; Smirnov, V.A.; Chashkin, R.Y. Measurements of isochoric heat capacities of near-critical argon. JETP Lett. 1969, 9, 229. Anisimov, M.A.; Berestov, A.T.; Veksler, L.S.; Koval’chuk, B.A.; Smirnov, V.A. Measurements of isochoric heat capacities of near-critical argon. Sov. Phys. JETP 1972, 39, 359. Anisimov, M.A.; Koval’chuk, B.A.; Smirnov, V.A. Experimental study of the isochore heat capacity of argon in a broad range of parameters of state, including the critical point. In Thermophysical Properties of Substances and Materials; Izd-vo Standartov: Moscow, Russia, 1975; pp. 237–245. (In Russian) Haupt, A.; Straub, J. Evaluation of the isochoric heat capacity measurements at the critical isochore of SF6 performed during the German Spacelab Mission D-2. Phys. Rev. 1999, E59, 1975–1986. Woodcock, L.V. On the interpretation of near-critical heat capacities. Int. J. Thermophys. 2017, 38, 139–144. [CrossRef] Michels, A.; Levelt, J.M.; de Graaff, W. Compressibility isotherms of argon at temperatures between −25 ◦C and −155 ◦C and at densities up to 60 amagat. Physica 1958, 24, 659–671. [CrossRef] Michels, A.; Levelt, J.M.; Wolkers, G.J. Compressibility isotherms of argon at temperatures between 0 ◦C and −155 ◦C and at densities up to 640 amagat. Physica 1958, 24, 769–794. [CrossRef] Anisimov, M.A. 50-Years of Breakthrough Discoveries in Fluid Criticality. Int. J. Thermophys. 2011, 32, 2003. [CrossRef] Bagatski ̆ı, M.I.; Voronel’, A.V.; Gusak, V.G. Measurements of isochoric heat capacities of near-critical argon. Sov. Phys. JETP 1963, 16, 517. Kostrowicka-Wyczalkowska, A.; Sengers, J.V. Thermodynamic properties of sulphur hexafluoride in the critical region. J. Chem. Phys. 1999, 111, 1551. [CrossRef] Mayer, J.E.; Mayer, M.G. Statistical Mechanics, 1st ed.; Wiley: New York, NY, USA, 1940; Chapter 14. Woodcock, L.V. Percolation transitions and fluid state boundaries. CMST 2017, 23, 281–294. [CrossRef] Tegeler, C.; Span, R.; Wagner, W. New equation of state for argon covering the fluid region for temperatures from the melting line to 700 K at pressures up to 1000 MPa. J. Phys. Chem. Ref. Data 1999, 28, 779–850. [CrossRef] Woodcock, L.V. Thermodynamics of supercritical colloidal equilibrium states: Hetero-phase fluctuations. Entropy 2019, 21, 1189. [CrossRef] © 2020 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (http://creativecommons.org/licenses/by/4.0/).

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