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Subject Index 201 Selmi sol 154, 157, 159, 161–164 Semiconductor 62 Settler 183 Sn molecule, enthalpy/entropy Sulfur bacteria 153–154, 163–164, 167–169, 171 Sulfur cation, enthalpy of formation 143 – –, hyperconjugation 149–150 – –, p bonding 146–148 – –, radical 138–139, 144, 146 – –, solid state structure 137 – –, solvation energy 144 – –, synthetic procedure 137 Sulfur chain, long 14 – –, –, branched 105 Sulfur cycle, biological 168 Sulfur compound oxidizing bacteria 167–181, 185 –, alkaliphilic 172, 183 Sulfur globules 167–181, 185 – –, Allochromatium vinosum 176 – –, Beggiatoa alba 176 Sulfur helix 48 Sulfur homocycle –, enthalpies of formation 101 –, isomer 39 –, mean bond energy 101 –, retention time 98 Sulfur inclusion envelope 177 Sulfur melts –, birefringence 89 –, doping 92 –, ESR spectra 91 –, fractional crystallization 94 –, glass-transition temperature 89 –, HPLC 97 –, Raman spectra 89, 94–95 Sulfur molecule, HOMO/LUMO gap 104 Sulfur radical cation 138–139, 144, 146 Sulfur ring 55 – –, branched 128 – –, Raman spectra 94 Sulfur sol, hydrophilic/hydrophobic 153–157, 160, 162 – –, LaMer 157 Sulfur vapor 117–119, 124–132 –, composition 117–129, 132 –, density 121, 124, 126 –, mass spectrometry 118–127, 132 –, partial pressure 120–121, 126 –, speciation, thermodynamic 117, 120–122, 125, 128 –, UV-Vis spectra 124 –, vibrational spectra 120–122, 129 Sulfurdichloride 5 Sulfuretum 169 Sulfuric acid production Superconducting state Surface charge density 125, 128–129, 132 SO2 emission 181, 185 Sol 153–162 –, monodispersed Sour gas 82 Stabilizer 15 Steric stabilization Structure, high-pressure phase 69 Sulfane monosulfonic acid Sulfate reducing bacteria Sulfide, chemical oxidation –, oxidation 171 158, 161–162 169 179 – radicals 180 Sulfur, colloidal –, commercial –, fibrous 15, 43, 45 –, flowers 15 112–113 –, superconducting e-Sulfur 17 m-Sulfur 87 –, properties p-Sulfur 84, 90, 98–107, 118–128, 54–57 – – , analysis – –, density – –, nomenclature – –, photochemical behavior – –, physical properties 52 – –, Raman spectra – –, solubility 55 – –, thermal behavior 184–185 60, 70 81, 84, 89 153–164 –, critical parameter –, helical structure –, high purity 92 –, melting curve 61 –, melting point depression –, metallic liquid 61 –, molecular nature 84, 87 –, preparation 84, 87 –, properties 81, 84 –, Raman spectra 94, 96 –, quantum-chemical calculation r-Sulfur 17 Sulfur allotropes 59 56 155 167, 173–174 153, 154, 164 6, 92, 102 –, high-purity –, insoluble 15 –, laminar 45 –, macromolecular –, polymeric 14, 56, 81–99, 102, 105–108, 7 41 60 101 67 85 117, 125 1, 3–4, 12, 17, 19, 47, 41 94–95 57 53 179 119–122,PDF Image | Topics in Current Chemistry
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