Volcanic Ash Degradation on Thermal Barrier Coatings

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Volcanic Ash Degradation on Thermal Barrier Coatings ( volcanic-ash-degradation-thermal-barrier-coatings )

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CHAPTER 4 VOLCANIC ASH AND ITS PENETRATION MECHNISMS IN TBCS SEM image of volcanic ash penetration into TBC top coat after exposed at 1250 °C for 3 hours is shown in Figure 4.15. It can be seen that volcanic ash penetrated into YSZ columnar gaps and pores, and great amount of volcanic ash was found at the bottom of YSZ top coat. In addition, spallation of TBC top coat was found in some part of the interface of top coat and TGO. It is believed that the aggregation of volcanic ash at the bottom of top coat might have caused the degradation of coating adherence and accelerated the spallation of TBC. Figure 4.15 SEM image of volcanic ash attack on TBC after 3 hours heat treatment at 1250 °C Figure 4.16 shows the cross-sectional microstructure of the volcanic ash penetrated TBC heat treated at 1250 °C for 10 hours. It was also noticed that considerable amount of volcanic ash was concentrated near the bottom of YSZ top coat which would eventually lead to the delamination of the top coat. However, unlike the CMAS attack on TBCs [40,42], there is no molten volcanic ash glass stayed inside of YSZ columnar pores. Referring to the EDX point analysis shown Page 59

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