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CONTENTS GLOSSARY ........................................................................................................................ xiii 1 INTRODUCTION ........................................................................................................ 1-1 2 SUMMARY ................................................................................................................. 2-1 SUPERCRITICAL CO2 PROPERTIES....................................................................... 2-1 COMMERCIALIZATION OF SUPERCRITICAL CO2 APPLICATIONS...................... 2-2 TECHNICAL ASPECTS ............................................................................................. 2-3 Supercritical CO2 Applications in Chemical Reactions .............................................. 2-3 Hydroformylation Reactions ................................................................................. 2-3 Hydrogenation Reactions ..................................................................................... 2-4 Oxidation Reactions ............................................................................................. 2-4 Case Study: Hydroformylation of Octene Using Supercritical CO2 Medium ........ 2-4 Supercritical CO2 Applications in Extractions ............................................................. 2-5 Case Study: General Extraction Processes ......................................................... 2-5 Supercritical CO2 Applications in Polymer Production and Processing ..................... 2-6 CO2 as a Polymerization Medium......................................................................... 2-6 CO2 as a Raw Material in Polymer Production..................................................... 2-7 Supercritical CO2 Applications in Polymer Processing ........................................ 2-8 Foaming of Polymer......................................................................................... 2-8 Spray Paint ...................................................................................................... 2-8 Dyeing of Textiles ............................................................................................ 2-8 Other Applications ........................................................................................... 2-8 Case Study: Fluoropolymer Production with Supercritical CO2 Polymerization Medium ................................................................................................................. 2-9 Case Study: Polycarbonate Production with Supercritical CO2 as a Raw Material ................................................................................................................. 2-10 Supercritical CO2 in Other Applications...................................................................... 2-11 Powder Production ............................................................................................... 2-11 Fabric Cleaning .................................................................................................... 2-12 Semiconductor Processing................................................................................... 2-12 © SRI Consulting iii PEP Report 269PDF Image | Abstract Process Economics Program Report 269 SUPERCRITICAL CO2: A GREEN SOLVENT
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