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FIGURES 4.1 Self-Diffusivity of Carbon Dioxide .......................................................................... 4-3 4.2 Viscosity of Carbon Dioxide .................................................................................. 4-4 4.3 Phase Diagram of Carbon Dioxide ........................................................................ 4-5 4.4 Typical Phase Behavior of Polymer-Solvent System ............................................ 4-7 4.5 Solubility of Polyethylene in Supercritical CO2 ...................................................... 4-8 4.6 Solubility of H2 in CO2-Expanded 1-Octene.......................................................... 4-12 5.1 BINAP Ligand for Asymmetric Hydroformylation of Styrene ................................. 5-4 5.2 BINAPOS Ligand for Asymmetric Hydroformylation of Styrene............................ 5-5 5.3 BARF Ligand for Asymmetric Hydroformylation of Styrene .................................. 5-5 5.4 Exxon Process for Isononyl Alcohol (INA) ............................................................ 5-13 5.5 Exxon Process for Isononyl Alcohol (INA): Catalyst Recovery ............................. 5-14 5.6 Supercritical CO2 for Hydroformylation ................................................................. 5-15 5.7 Hydroformylation of Octene Using Supercritical CO2............................................ E-3 5.8 Nonyl Aldehyde Production with Supercritical CO2: Effect of Rhodium Catalyst Loss on Nonyl Aldehyde Product Value ................................................................ 5-28 6.1 Simplified Flow Diagram of Supercritical CO2 Extraction Processes.................... 6-2 6.2 Supercritical Fluid Extraction for β-Carotene and Lutein Production .................... 6-3 6.3 Multi-unit Process for Phospholipid Production..................................................... 6-4 6.4 Supercritical CO2 Hop Extractor ............................................................................ 6-6 6.5 Extraction with Low Pressure Recycling ............................................................... 6-10 6.6 Extraction with High Pressure Recycling .............................................................. 6-11 6.7 Estimated Battery Limits Investment (BLI) for Supercritical CO2 Extraction Processes .............................................................................................................. 6-14 6.8 Estimated Total Direct Costs for Supercritical CO2 Extraction Processes............ 6-15 7.1 UniCarbTM Coating Process .................................................................................. 7-11 7.2 General Structure of FEP Copolymer.................................................................... 7-12 7.3 FEP Resin by Continuous Precipitation Polymerization Process with CO2 Medium .................................................................................................................. E-5 7.4 Separator ............................................................................................................... 7-18 © SRI Consulting ix PEP Report 269PDF Image | Abstract Process Economics Program Report 269 SUPERCRITICAL CO2: A GREEN SOLVENT
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