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Chemical Processes and Use of CO2

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Chemical Processes and Use of CO2 ( chemical-processes-and-use-co2 )

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1CO2 UTILIZATION DREAMREACTION CO2 and epichlorohydrin to produce a cyclic carbonate, however, subse- quent transesterification of the cyclic carbonate to form DPC failed. 1.2.4 Exploitation, commercialisation and dissemination of results The fundamental research work carried out in the ‘Dream Reactions’ pro- ject has yielded important information, particularly with respect to cata- lytic routes to polyether polycarbonate polyols, and this has opened up new avenues to explore in future projects. Process scale-up and the production of the first sample quantities were achieved in the BMBF-funded follow-up project ‘Dream Production’. In ad- dition to examining the use of industrial CO2 from a power plant, the ‘Dream Production’ project also conducted a systematic LCA of the overall process. The results concerning the catalysed production of polyether polycarbonate polyols acquired during the ‘Dream Reactions’ and ‘ Dream Production’ pro- jects provide a basis for future commercialisation. Building on the results of the ‘Dream’ projects, a plant with a production capacity of 5000 metric tons of PPP per year has been established in Dormagen Industry Park in order to demonstrate the feasibility of producing CO2-based polyols on a commerci- al scale. The project was showcased as part of an exhibition stand at the 2016 Woche der Umwelt (‘Environment Week’), which was organised by the Ger- man Federal Environmental Foundation (DBU) and the Office of the Federal President in Bellevue Palace in Berlin. The project results and findings were disseminated to the scientific com- munity via presentations at conferences and publications in international journals (Green Chemistry, ChemSusChem, etc.). A number of Diplom and PhD research theses were completed over the course of the project and two patents were also registered. References: https://www.woche-der-umwelt.de/ (retrieved on 24 June 2016) 36

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