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Chemical Processes and Use of CO2

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Chemical Processes and Use of CO2 ( chemical-processes-and-use-co2 )

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DREAM PRODUCTION FUNDED PROJECTS tal aspects of the activation of CO2. A life cycle assessment study was con- ducted in WP7 in order to address environmental impact issues relevant to the project. Figure 15 shows an overview of the component work packages within the collaborative project. 1.4.3 Results As part of the ‘Dream Production’ project, the pilot-scale carbon capture system at the RWE power plant in Niederaußem was expanded by adding a liquefaction and filling unit. The CO2 recovered from the carbon capture system was made available to all of the project partners. Irrespective of the type of purification method used, the quality of the industrially recovered CO2 was always of a quality high enough for it be employed in the proposed synthesis reactions. In order to produce samples of the polyether carbonate polyols in sufficient quantities, the laboratory-scale production system used in the preceding project was scaled up appropriately (see Figure 16). This mini-plant was used to develop the production process and to optimise the composition of the reaction mixture used in fabricating the polyether carbonate polyols. Plant operating modes of increasing complexity were employed, starting with a semi-batch system, which was followed by a continued-addition-of-starter (CAOS) semi-batch set-up, and finally a CAOS continuous process. The mini-plant enabled sample quantities of different types of polyether carbonate polyols to be produced and tested in a variety of polyurethane Fig. 16: The completed mini-plant for the production of CO2-containing polyols 47

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