Chemical Processes and Use of CO2

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Chemical Processes and Use of CO2 ( chemical-processes-and-use-co2 )

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DMEEXCO2 FUNDED PROJECTS model of the catalyst, which is necessary if the reactor is to undergo success- ful industrial scale-up. The project succeeded in demonstrating that replacing the current two-step production of DME (via methanol) with the direct DME synthesis process developed during the project results in a reduction in carbon emissions of 30%. The new process also yields competitive benefits thanks to energy effi- ciency improvements of around 10%, which are also reflected in the positive rating of the economic viability of the new process. Fig. 26: Benchmarking of the conventional (two-step) versus the new one-step process DME Natural gas synthesis gas production Natural gas synthesis gas production MeOH- Synthesis DME- Synthesis Syngas Syngas DME 1.8.4 Exploitation, commercialisation and dissemination of results In this collaborative project, a process for synthesising DME was developed that exhibits technological and commercial advantages when compared to the process currently used. Increasingly, DME is being added to LPG to pro- duce LPG/DME blends. DME may also acquire a future share of the market in diesel fuels. The advantages of DME are principally due to the fact that it exhibits better combustion properties (including emissions) compared to pure LPG and diesel. Commercial exploitation of DME will depend on the prevailing regulatory conditions and on market competitiveness. The pro- ject has demonstrated that DME is economically competitive by decoupling the cost of DME production from the price of methanol. Building on the de- velopment work in the project, a pilot phase will need to be carried out prior to any future commercialisation. Current forecasts show a slightly smaller growth rate for the DME market than was the case at the beginning of the project in 2011; the growth rate is, however, significantly above average growth rates. The sizeable investment required for new plants represents a significant opportunity for process plant construction companies and for catalyst manufacturers. The goal of the industrial project partners remains that of continuing to de- velop the direct synthesis of DME in partnership with others and to com- mercialise the results if positive. MeOH DME- Synthesis Conventional DME-Synthesis via MeOH Direct DME-synthesis Cold gas efficiency Benchmark >10% improvement CO2-Emission Benchmark > 30% reduction 73

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