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CARBON CAPTURE A conventional combustion process with air generates flue gas that, in addi- tion to various trace substances, contains CO2, H2O and inert nitrogen N2. In the oxy-combustion process, the flue gas contains only CO2 and H2O. The water can be removed by condensing it cryogenically, i.e. by cooling the flue gas stream below the condensation temperature of the water vapour, leaving a CO2-rich gas stream. As combustion with pure oxygen would lead to unacceptably high temperatures, most of the cleaned and cooled flue gas has to be returned to the boiler (Fig. 80a). As a result, the CO2 stream becomes enriched with components such as SO2, whose removal has a negative effect on the cost effectiveness of the overall process. A simplified schematic of the carbon capture and flue gas cleaning process is shown in Figure 80b Fuel Air Air separation N2 Boiler Gas cleaning Atmospheric H2O- Condensation CCGT with H2-turbine CO2 Fig. 80a: Simplified schematic of an oxy-combustion capture process Fig. 80b: Schematic of carbon capture stage in an oxy-fuel steam turbine cycle [1] 185PDF Image | Chemical Processes and Use of CO2
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