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3 ENERGY-EFFICIENT PROCESSES The strength of the associations shown in the table above range from the simple compatibility of a particular physicochemical separation technique with a particular carbon capture technology to pairings that reflect the cur- rent state of the art in industrial applications. For any real-life application, an assessment has to be made based on the in- dividual weighting of the relevant technical and economic factors. The ma- trix shown above should therefore only be used to assist in the initial selec- tion of suitable CO2 separation technique for use in a particular application. In thermal, fossil-fuel-fired power plants and thermoprocessing equipment, the primary energy source is converted by means of a conventional combus- tion process. The following sections therefore focus on the selection and use of an amine-based chemical absorption method and explain a number of the important process design parameters. 3.1.3 Chemical absorption as a post-combustion carbon capture process for a power plant 3.1.3.1 Choice of solvent (absorbent) Using chemical absorption to remove CO2 from the flue gas stream in a post-combustion process typically involves selecting one of the following substance classes as the liquid solvent: • Alkanolamines • Alkali carbonates • Amino acid salts • Ionic liquids • Ammonia. The two most important properties in selecting the solvent are: • The rate of reaction for the CO2 absorption step • The energy requirements for the absorption step and for the desorption of bound CO2. 188PDF Image | Chemical Processes and Use of CO2
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