CO2 Separation with Ionic Liquids

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CO2 Separation with Ionic Liquids ( co2-separation-with-ionic-liquids )

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The excess molar enthalpy of aqueous ChCl/Urea has been measured in our research group [132]. In order to gain insight into the excess properties, the results at 308.2 K were shown in Figure 4.15. It can be seen that the excess molar enthalpy of aqueous ChCl/Urea exhibits an “S-shaped” behavior. In the ChCl/Urea-rich region, the value of excess molar enthalpy is negative, indicating the exothermic process. When the mole fraction of water is around 0.6, the value of excess molar enthalpy is zero. In the H2O-rich region, the value changes to positive, and this implies that the mixing process is endothermic. Figure 4.15. The excess molar enthalpy of the mixture of (ChCl/Urea + H2O). As shown in Figure 4.16, the excess part of the Henry’s constant of CO2 in aqueous ChCl/Urea decreases with the increase of water content in the investigated range (xH2O < 0.6). The current experimental results cannot provide the exact value, but theoretically, there will be a minimum value within the range of (0.6 < xH2O < 1). Figure 4.16. The excess Henry’s constant of CO2 in the mixture of (ChCl/Urea + H2O). 36

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