CO2 Separation with Ionic Liquids

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CO2 Separation with Ionic Liquids ( co2-separation-with-ionic-liquids )

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For CO2-H2O-ChCl/Urea and CO2-H2O-[Amim][HCOO] systems, the parameters between H2O and IL (ChCl/Urea, [Amim][HCOO]) were fitted to the solubility of CO2 in aqueous ChCl/Urea and aqueous [Amim][HCOO], respectively. For the gas mixture (e.g. the mixture of CO2 and CH4), no additional adjustable parameters between CO2 and CH4 were used to calculate the fugacity coefficient in the vapor phase. The parameters in NRTL model can be fitted to the solubility of gas mixture in a solvent. The solubility of the mixture of CO2 and CH4 was not available for all two studied novel ILs in this work, therefore, the NRTL model parameters between CO2 and CH4 were obtained from the fitting of experimental solubility of (CO2 + CH4) in [bmim][Tf2N] [134]. These fitted parameters were considered as transferable and used for predicting the solubility of the mixture of CO2 and CH4 in other ILs or aqueous ILs. All the parameters are summarized in Tables 4.7 and 4.8. Table 4.7. The parameters of Henry’s constant (MPa) and characteristic volume (υ1 and υ2). gas solvent CO2 [hmim][Tf2N] CH4 [hmim][Tf2N] CO2 [bmim][Tf2N] CH4 [bmim][Tf2N] CO2 [bmim][PF6] CH4 [bmim][PF6] CO2 ChCl/Urea CH4 ChCl/Urea CO2 [Amim][HCOO] CH4 [Amim][HCOO] CO2 H2O CH4 H2O h1 h2 6.52 -1617.9 4.066 -418.5 6.83 -1695.1 4.848 -303.2 8.32 -2001.8 7.807 -873.9 7.655 -1599.3 6.196 -752.4 8.191 -2286.4 10.05 -1765.2 h1 h2 157.56 -8741.6 181.48 -9111.7 υ1 υ2 17.193 0.556 - - 220.5 -0.0735 - - 8.079 0.277 - - 0.263 - 0.0992 - - - - - h3 h4 -21.669 0.0011026 -25.038 0.00014343 40

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