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Sustain. Chem. 2021, 2 321 40. Monbaliu, J.-C.M.; Winter, M.; Chevalier, B.; Schmidt, F.; Jiang, Y.; Hoogendoorn, R.; Kousemaker, M.A.; Stevens, C.V. Effective production of the biodiesel additive STBE by a continuous flow process. Bioresour. Technol. 2011, 102, 9304–9307. [CrossRef] 41. Solketal: An EHS Friendly and Sustainable Solvent; IMPAG Switzerland: Zürich, Switzerland, 2017. 42. National Center for Biotechnology Information. PubChem Compound Summary for CID 7528, Solketal. Available online: https://pubchem.ncbi.nlm.nih.gov/compound/Solketal (accessed on 13 December 2020). 43. Esteban, J.; García-Ochoa, F.; Ladero, M. Solventless synthesis of solketal with commercially available sulfonic acid based ion exchange resins and their catalytic performance. Green Process. Synth. 2017, 6, 79–89. [CrossRef] 44. Melero, J.A.; Vicente, G.; Morales, G.; Paniagua, M.; Bustamante, J. Oxygenated compounds derived from glycerol for biodiesel formulation: Influence on EN 14214 quality parameters. Fuel 2010, 89, 2011–2018. [CrossRef] 45. Isac-García, J.; Dobado, J.A.; Calvo-Flores, F.G.; Martínez-García, H. Chapter 5—Determining physical and spectroscopic properties. In Experimental Organic Chemistry; Isac-García, J., Dobado, J.A., Calvo-Flores, F.G., Martínez-García, H., Eds.; Academic Press: Cambridge, MA, USA, 2016; pp. 145–175. ISBN 978-0-12-803893-2. 46. Alptekin, E. Emission, injection and combustion characteristics of biodiesel and oxygenated fuel blends in a common rail diesel engine. Energy 2017, 119, 44–52. [CrossRef] 47. Ilgen, O.; Yerlikaya, S.; Akyurek, F.O. Synthesis of solketal from glycerol and acetone over amberlyst-46 to produce an oxygenated fuel additive. Period. Polytech. Chem. Eng. 2016. [CrossRef] 48. Nanda, M.R.; Zhang, Y.; Yuan, Z.; Qin, W.; Ghaziaskar, H.S.; Xu, C. Catalytic conversion of glycerol for sustainable production of solketal as a fuel additive: A review. Renew. Sustain. Energy Rev. 2016, 56, 1022–1031. [CrossRef] 49. Fischer, E. Ueber die Verbindungen der Zucker mit den Alkoholen und Ketonen. Ber. Dtsch. Chem. Ges. 1895, 28, 1145–1167. [CrossRef] 50. Newman, M.S.; Renoll, M. Improved preparation of isopropylidene glycerol. J. Am. Chem. Soc. 1945, 67, 1621. [CrossRef] 51. Nanda, M.R.; Yuan, Z.; Qin, W.; Ghaziaskar, H.S.; Poirier, M.-A.; Xu, C. Catalytic conversion of glycerol to oxygenated fuel additive in a continuous flow reactor: Process optimization. Fuel 2014, 128, 113–119. [CrossRef] 52. García, E.; Laca, M.; Pérez, E.; Garrido, A.; Peinado, J. New class of acetal derived from glycerin as a biodiesel fuel component. Energy Fuels 2008, 22, 4274–4280. [CrossRef] 53. Nanda, M.R.; Yuan, Z.; Qin, W.; Ghaziaskar, H.S.; Poirier, M.-A.; Xu, C.C. Thermodynamic and kinetic studies of a catalytic process to convert glycerol into solketal as an oxygenated fuel additive. Fuel 2014, 117, 470–477. [CrossRef] 54. Roldán, L.; Mallada, R.; Fraile, J.M.; Mayoral, J.A.; Menéndez, M. Glycerol upgrading by ketalization in a zeolite membrane reactor. Asia-Pac. J. Chem. Eng. 2009, 4, 279–284. [CrossRef] 55. Maksimov, A.L.; Nekhaev, A.I.; Ramazanov, D.N.; Arinicheva, Y.A.; Dzyubenko, A.A.; Khadzhiev, S.N. Preparation of high-octane oxygenate fuel components from plant-derived polyols. Pet. Chem. 2011, 51, 61–69. [CrossRef] 56. Serafim, H.; Fonseca, I.M.; Ramos, A.M.; Vital, J.; Castanheiro, J.E. Valorization of glycerol into fuel additives over zeolites as catalysts. Chem. Eng. J. 2011, 178, 291–296. [CrossRef] 57. Ruiz, V.R.; Velty, A.; Santos, L.L.; Leyva-Pérez, A.; Sabater, M.J.; Iborra, S.; Corma, A. Gold catalysts and solid catalysts for biomass transformations: Valorization of glycerol and glycerol–water mixtures through formation of cyclic acetals. J. Catal. 2010, 271, 351–357. [CrossRef] 58. Da Silva, C.X.A.; Gonçalves, V.L.C.; Mota, C.J.A. Water-tolerant zeolite catalyst for the acetalisation of glycerol. Green Chem. 2009, 11, 38–41. [CrossRef] 59. Deutsch, J.; Martin, A.; Lieske, H. Investigations on heterogeneously catalysed condensations of glycerol to cyclic acetals. J. Catal. 2007, 245, 428–435. [CrossRef] 60. Rodrigues, A.E.; Madeira, L.M.; Wu, Y.-J.; Faria, R. Sorption Enhanced Reaction Processes; World Scientific Publishing Co Pte Ltd.: Singapore, 2017; ISBN 978-1-78634-356-7. 61. De Torres, M.; Jiménez-osés, G.; Mayoral, J.A.; Pires, E.; de los Santos, M. Glycerol ketals: Synthesis and profits in biodiesel blends. Fuel 2012, 94, 614–616. [CrossRef] 62. Faria, R.P.V.; Pereira, C.S.M.; Silva, V.M.T.M.; Loureiro, J.M.; Rodrigues, A.E. Glycerol valorization as biofuel: Thermodynamic and kinetic study of the acetalization of glycerol with acetaldehyde. Ind. Eng. Chem. Res. 2013, 52, 1538–1547. [CrossRef] 63. Faria, R.P.V.; Pereira, C.S.M.; Silva, V.M.T.M.; Loureiro, J.M.; Rodrigues, A.E. Glycerol valorisation as biofuels: Selection of a suitable solvent for an innovative process for the synthesis of GEA. Chem. Eng. J. 2013, 233, 159–167. [CrossRef] 64. Bruchmann, B.; Haberle, K.; Gruner, H.; Hirn, M. Preparation of Cyclic Acetals or Ketals. U.S. Patent No. US5917059A, 29 June 1999. 65. Royon, D.; Locatelli, S.; Gonzo, E.E. Ketalization of glycerol to solketal in supercritical acetone. J. Supercrit. Fluids 2011, 58, 88–92. [CrossRef] 66. Eigenberger, G.; Ruppel, W. Catalytic fixed-Bed reactors. In Ullmann’s Encyclopedia of Industrial Chemistry; Wiley-Vch: Weinheim, Germany, 2012; ISBN 9783527303854. 67. Clarkson, J.S.; Walker, A.J.; Wood, M.A. Continuous reactor technology for ketal formation: An improved synthesis of solketal. Org. Process Res. Dev. 2001, 5, 630–635. [CrossRef] 68. Cablewski, T.; Faux, A.F.; Strauss, C.R. Development and application of a continuous microwave reactor for organic synthesis. J. Org. Chem. 1994, 59, 3408–3412. [CrossRef] 69. Kowalska-Kus, J.; Held, A.; Frankowski, M.; Nowinska, K. Solketal formation from glycerol and acetone over hierarchical zeolites of different structure as catalysts. J. Mol. Catal. A Chem. 2017, 426, 205–212. [CrossRef]PDF Image | Continuous Valorization of Glycerol into Solketal
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