Electrocatalytic Processes for the Valorization of CO2

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Catalysts 2019, 9, 413 11 of 12 22. Xie, J.N.; Yu, B.; Zhou, Z.H.; Fu, H.C.; Wang, N.; He, L.N. Copper(I)-Based Ionic Liquid-Catalyzed Carboxylation of Terminal Alkynes with CO2 at Atmospheric Pressure. Tetrahedron Lett. 2015, 56, 7059–7062. [CrossRef] 23. Isse, A.A.; Ferlin, M.G.; Gennaro, A. Electrocatalytic Reduction of Arylethyl Chlorides at Silver Cathodes in the Presence of Carbon Dioxide: Synthesis of 2-Arylpropanoic Acids. J. Electroanal. Chem. 2005, 581, 38–45. [CrossRef] 24. Senboku, H.; Nagakura, K.; Fukuhara, T.; Hara, S. Three-Component Coupling Reaction of Benzylic Halides, Carbon Dioxide, and N,N-Dimethylformamide by Using Paired Electrolysis: Sacrificial Anode-Free Efficient Electrochemical Carboxylation of Benzylic Halides. Tetrahedron 2015, 71, 3850–3856. [CrossRef] 25. Cruz, H.; Gallardo, I.; Guirado, G. Electrochemically Promoted Nucleophilic Aromatic Substitution in Room Temperature Ionic Liquids-An Environmentally Benign Way to Functionalize Nitroaromatic Compounds. Green Chem. 2011, 13, 2531–2542. [CrossRef] 26. Dokania, A.; Ramirez, A.; Bavykina, A.; Gascon, J. Heterogeneous Catalysis for the Valorization of CO2: Role of Bifunctional Processes in the Production of Chemicals. ACS Energy Lett. 2018, 4, 167–176. [CrossRef] 27. Isse, A.A.; Durante, C.; Gennaro, A. One-Pot Synthesis of Benzoic Acid by Electrocatalytic Reduction of Bromobenzene in the Presence of CO2. Electrochem. Commun. 2011, 13, 810–813. [CrossRef] 28. Senboku, H.; Katayama, A. Electrochemical Carboxylation with Carbon Dioxide. Curr. Opin. Green Sustain. Chem. 2017, 3, 50–54. [CrossRef] 29. Zhao, G.; Huang, X.; Wang, X.; Wang, X. Progress in Catalyst Exploration for Heterogeneous CO2 reduction and Utilization: A Critical Review. J. Mater. Chem. A 2017, 5, 21625–21649. [CrossRef] 30. Tahara, H.; Uranaka, K.; Hirano, M.; Ikeda, T.; Sagara, T.; Murakami, H. Electrochromism of Ferrocene and Viologen-Based Redox-Active Ionic Liquids Composite. ACS Appl. Mater. Interfaces 2018, 11, 1–6. [CrossRef] 31. Mao, X.; Wu, M.; Xu, X.; Jiang, L.; Yan, J.; Du, Z.; Li, J.; Hou, S. Fabrication of an Electrochemical Sensor for NOx Based on Ionic Liquids and MoS2. Int. J. Electrochem. Sci. 2018, 13, 11038–11048. [CrossRef] 32. Thompson, M.W.; Matsumoto, R.; Sacci, R.L.; Sanders, N.C.; Cummings, P.T. Scalable Screening of Soft Matter: Case Study of Mixtures of Ionic Liquids and Organic Solvents. J. Phys. Chem. B 2019, 123, 1340–1347. [CrossRef] [PubMed] 33. Reche, I.; Gallardo, I.; Guirado, G. Electrochemical Studies of CO2 in Imidazolium Ionic Liquids Using Silver as a Working Electrode: A Suitable Approach for Determining Diffusion Coefficients, Solubility Values, and Electrocatalytic Effects. RSC Adv. 2014, 4, 65176–65183. [CrossRef] 34. Alvarez-Guerra, M.; Albo, J.; Alvarez-Guerra, E.; Irabien, A. Ionic Liquids in the Electrochemical Valorisation of CO2. Energy Environ. Sci. 2015, 8, 2574–2599. [CrossRef] 35. Chong, F.K.; Andiappan, V.; Ng, D.K.S.; Foo, D.C.Y.; Eljack, F.T.; Atilhan, M.; Chemmangattuvalappil, N.G. Design of Ionic Liquid as Carbon Capture Solvent for a Bioenergy System: Integration of Bioenergy and Carbon Capture Systems. ACS Sustain. Chem. Eng. 2017, 5, 5241–5252. [CrossRef] 36. Gallardo, I.; Soler, S. Electrochemically Promoted Arylation of Iodoaromatics. J. Electroanal. Chem. 2017, 799, 9–16. [CrossRef] 37. Isse, A.A.; Falciola, L.; Mussini, P.R.; Gennaro, A. Relevance of Electron Transfer Mechanism in Electrocatalysis: The Reduction of Organic Halides at Silver Electrodes. Chem. Commun. 2006, 1, 344–346. [CrossRef] 38. Isse, A.A.; Gottardello, S.; Durante, C.; Gennaro, A. Dissociative Electron Transfer to Organic Chlorides: Electrocatalysis at Metal Cathodes. Phys. Chem. Chem. Phys. 2008, 10, 2409–2416. [CrossRef] 39. Isse, A.A.; Berzi, G.; Falciola, L.; Rossi, M.; Mussini, P.R.; Gennaro, A. Electrocatalysis and Electron Transfer Mechanisms in the Reduction of Organic Halides at Ag. J. Appl. Electrochem. 2009, 39, 2217–2225. [CrossRef] 40. Arnaboldi, S.; Bonetti, A.; Giussani, E.; Mussini, P.R.; Benincori, T.; Rizzo, S.; Isse, A.A.; Gennaro, A. Electrocatalytic Reduction of Bromothiophenes on Gold and Silver Electrodes: An Example of Synergy in Electrocatalysis. Electrochem. commun. 2014, 38, 100–103. [CrossRef] 41. Costentin, C.; Robert, M.; Savéant, J.-M. Catalysis of the Electrochemical Reduction of Carbon Dioxide. Chem. Soc. Rev. 2013, 42, 2423–2436. [CrossRef] [PubMed] 42. Gennaro, A.; Isse, A.A.; Save, J.; Severin, M.; Vianello, E.; Pado, V.; Loredan, V.; Diderot, D.; Cedex, P.; February, R.V.; et al. Homogeneous Electron Transfer Catalysis of the Electrochemical Reduction of Carbon Dioxide. Do Aromatic Anion Radicals React in an Outer-Sphere Manner? J. Am. Chem. Soc. 1996, 118, 7190–7196. [CrossRef]

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