ENVIRONMENTAL CHEMISTRY

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ENVIRONMENTAL CHEMISTRY ( environmental-chemistry )

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ENVIRONMENTAL CHEMISTRY group of pesticides thus making the pesticides ineffective. Therefore, as insect resistance of DDT increased, other organic toxins such as Aldrin and Dieldrin were introduced in the market by pesticide industry. Most of the organic toxins are water insoluble and non- biodegradable. These high persistent toxins are, therefore, transferred from lower trophic level to higher trophic level through food chain (Fig.14.3). Over the time, the concentration of toxins in higher animals reach a level which causes serious metabolic and physiological disorders. Fig. 14.3 At each trophic level, the pollutant gets 10 times concentrated. In response to high persistence of chlorinated organic toxins, a new series of less persistent or more bio-degradable products called organo-phosphates and carbamates have been introduced in the market. But these chemicals are severe nerve toxins and hence more harmful to humans. As a result, there are reports of some pesticides related deaths of agricultural field workers. Insects have become resistant to these insecticides also. The insecticide industry is engaged in developing new groups of insecticides. But one has to think, is this the only solution to pest menace? These days, the pesticide industry has shifted its attention to herbicides such as 417 sodium chlorate (NaClO3), sodium arsinite (Na3AsO3) and many others. During the first half of the last century, the shift from mechanical to chemical weed control had provided the industry with flourishing economic market. But one must remember that these are also not environment friendly. Most herbicides are toxic to mammals but are not as persistent as organo-chlorides. These chemicals decompose in a few months. Like organo-chlorides, these too become concentrated in the food web. Some herbicides cause birth defects. Studies show that corn- fields sprayed with herbicides are more prone to insect attack and plant disease than fields that are weeded manually. Pesticides and herbicides represent only a very small portion of widespread chemical pollution. A large number of other compounds that are used regularly in chemical and industrial processes for manufacturing activities are finally released in the atmosphere in one or other form. 14.5 INDUSTRIAL WASTE Industrial solid wastes are also sorted out as biodegradable and non-degradable wastes. Biodegradable wastes are generated by cotton mills, food processing units, paper mills, and textile factories. Non-biodegradable wastes are generated by thermal power plants which produce fly ash; integrated iron and steel plants which produce blast furnace slag and steel melting slag. Industries manufacturing aluminium, zinc and copper produce mud and tailings. Fertilizer industries produce gypsum. Hazardous wastes such as inflammables, composite explosives or highly reactive substances are produced by industries dealing in metals, chemicals, drugs, pharma- ceuticals, dyes, pesticides, rubber goods etc. The disposal of non-degradable industrial solid wastes, if not done by a proper and suitable method, may cause serious threat to the environment. New innovations have led to different uses of waste material. Nowadays, fly ash and slag from the steel industry are utilised by the cement industry. Large 2019-20

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