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APPENDIX 1: EVALUATION OF KPI Table 11: Costs breakdown and assumed parameters. When an interval is mentioned, the first value corresponds to a process with higher TRL (i.e. the MeOH process), while the second one corresponds to a process with lower TRL (i.e. the FA process) [54]. Total fixed capital cost (TFCC) CAPEX Variable costs of production (VCP) Fixed costs of production (FCP) ISBL capital costs OSBL capital costs Engineering costs Contingency Working capital TFCC + Working capital Raw materials costs By-products disposal Catalyst consumption Utilities consumption Salaries and overheads Maintenance Interest Royalties Factorial methodology 35% of ISBL 20-30% of ISBL and OSBL 30% of ISBL and OSBL 15-20% of ISBL and OSBL Market prices (Table 12) and model results 5-4 operators [112]; 78 000 €/yr [163] Supervision is 25 % of operating labour Overhead is 45% of labour and supervision Tax and insurance are 2 % of TFCC 3 % of ISBL 6 % of working capital None Table 12: Prices considered in the economic KPIs, in €2014. Item CO2 captured Water Cooling water High pressure steam Medium pressure steam Electricity Oxygen Methanol Formic acid Copper-based catalyst (MeOH) Ruthenium-based catalyst (FA) Phosphino-based catalyst (FA) Amine (FA) Price 38.4 €/tCO2 1 €/tH2O 0.025 €/tH2O 25.12 €/tH2O 22.83 €/tH2O 95.09 €/MWh 54.2 €/tO2 350 €/tMeOH 650 €/tFA 95.2 €/kgcat 210 000 €/kgcat 84 900 €/kgcat 724 €/kgcat Source [161] [54], [57] [54], [57] [54], [57] [54], [57] [57], [164] [165] [166] [122], [167] [168] [169] [153] [170] 79PDF Image | evaluation of CO2 utilisation for fuel production
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