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Polymers 2017, 9, 626 5 of 15 Polymers 2017, 9, 626 5 of 15 The FTIR spectra of pure PMMA polar polymer and PMMA doped with 28 mL of extract GT solution areshownininFFigiguurerses33anadnd4.4F.TFITRIRspsepctercotsrcoospcoyphyashalosnlgonbgeebnereencorgecnoizgendizaesdaapsoawpeorfwuletrofuol tfoorlthfoereltuhceidealuticoindaotfiostnruocftusrtraulcintuforramliantfionrm.Tahtieopno.sTithieonp,oinsitteinosni,tyi,natnendssithya,paenodfvshibarpaetionfavlibarnatdisonaarel buasnefduslianrcelaurisfeyfiunlgicnoncfloarrmifyatiinognacloanfdoremnvaitrionmalenantadlcehnavnigreosnomfepnotlaylmcehrasnagtetsheomfoploeclyumlarerlsevaetl[t2h2e]. mItowleacsuwlaerlleevsetalb[l2i2s]h.eIdttwhastfwunelcltieosntabllgisrhoeudpsthinatofrugnacntiiconcoaml gprounpdssinhaovreganbiscorcpotmiopnosuwndhischavre −1 achbsaorarpcteiorinssticwnhoicthonalryeicnhparoascitieornis,tbicuntoatlsonilnyiintepnossiittyio[n23, ]b.uTthaelsotrionnignbteansdityap[p23e]a.rTinhgeastr1o7n2g6 cbmand −1 ainpptheearsinpgecattru1m726(scemeFiignutrhee3s)poefctrhuemp(usreePFMiguMrAe3s)aomfpthlepcaunrebPeMatMtrAibusatemdptloetchaencbaerbatotnriyblu(tCed=Oto) −1 tghreoucaprb[2o2n]yaln(Cd=sOh)ifgtsrotuop17[212]camnd shwifitshtolo1w7e1r2 icnmtenwsitiythalnodwebroinatdencshiatyracntedrbirnotahdecdhoarpaecdtePrMinMthAe −1 dsaompepdleP(MseeMFAigsuarme 4p)l.eT(hseues,Ftihgeusrehi4ft).inThpueas,ktphoessithioifnt,idnepcreeaaksepionsitniotenn,sditeyc,raenadsebirnoaidnteennisnigtyo,fatnhde bpreoaakddeuneintgoothfethCe=pOeainktdhueedtoptehdePCM=OMAinstahmepdloepceledaPrlMyiMndAicsaatmesptlheecmleiasrcliybilnitdyicbaetewsetehnetmheisPciMbiMlitAy −1 Tath3e4b3a3ncdmappienatrheedFaTtI3R43sp3ecmtra oinf pthuereFPTMIRMspAeicstraeloaftepdutroetPhMe NM–AHistretlcahteindgtovitbhreatNio–nH[2s5t,r2e6tc],haingd −1 baentdwGeeTnetxhteraPcMt sMolAutainodn.GTThexFtrTaIcRt sboalnudtisonap. TpheearFinTgIRfrboamnd9s5a0p–p4e8a1rcinmg froinmF9i5g0u–r4e8s13camndi4n aFrigeudruees −1 3toatnhde4beanredidnugeotfoCth–Heb[e2n4d].inTgheofpCea–kHa[t2249]3.5Thcmepea(kFiagtu2r9e335)cmanb(Feiagsucreib3e)dcaton–bCeHassctrriebtecdhitnog–aCnHd −1 sthrieftcshtion2g94a3ndinsthieftdsotpoe2d9P43MiMnAthseadmopled(FPigMuMreA3)saanmdpalene(Fwigpueraek3a)ta2n84d7acmnewapepaekaraetd2,8w47hicmh is −1 apttpriebaurteed, wtohciacrhbiosxaytltircibaucitdedgrtoucpasrboofxtyhleicGaTciedxgtraocutpssolouftitohne (GseTeeFxitgraucrtes2o)l[u1t8io].nT(hseebFaingduraep2p)e[a1r8e]d. −1 −1 vshibifrtastiton34[2352,2c6m], anwdisthiaftsitgon3ifi43ca2nctmdecwreiathseainsigintiefincsaintyt dasecdrepaisceteindinteFnigsuitryea3s. dTehpeicvtaelduainblFeicghuarneg3e. −1 TinhienvteanlusiatbyleofchNa–nHgebiandinitsenasniteyvoidfeNn–cHefobranadlairsgaenaemvoiduenntcoeffNor–Ha lafurgnectaiomnoaulngtroufpNs–iHnGfuTnecxtitornacatl. gArdoduiptisoninalGlyT, tehxetFraTcItR. AspdedcittriaonofalGlyT, ethxetraFcTtIsRolsupteiocntra(soeef GFiTguerxetr2a)csthsowlusttiohne e(sxeiseteFnigceuroef a2)Ns–hHowgsrotuhpe −1 ewxitshtesntrcoenogf ainNte–nHsitgyroaut p34w01ithcmstro.nTghinutse,nthsietydaetcr3e4a0s1ecimn in.tTenhsuist,ytohfetdhecIrReabsaenindiantte3n43si2tycmofctahne IbRe −1 baascnrdibaetd 3t4o3t2hecmcomcapnlebxefoarsmcriabteiodntboethweeecnomthpeleGxTfoexrmtractitosnolbuettiwoneeandthPeMGMTAexptoralyctmseorl.uTtihoenFaTnIRd PspMecMtrAumpoolfympuere. TPhMeMFTAIRobstpaeincterdumin tohfeppuresePnMt MwoArkobistavienreydsinmtihlaerptoretsheanttrwepoorrkteisdvbeyrySosmimainlaarntdo tKhealtkraerp[o2r7t]e.dThbeysShoimftianngaindthKeeFlTkaIRr [b2a7n].dTshaendshtihfteindgecinretahse FinTiInRtebnasnitdysiasnedvitdhendcecfroeratsheeinocicnuterrnesnitcye iosfemvidsceinbcileitfyorbtehtwe oececnutrhrenPcMe oMfAmipsocilbyimliteyr banetdwtehenGthTeePxMtraMctAsoploultyiomne.r and the GT extract solution. −1 −1 Transmittance (a.u) 3611 3541 3433 2043 1954 2935 3900 3400 2900 2400 1726 1369 747 481 400 wavenumber (cm-1) Figure 3. FTIR spectra of pure PMMA polymer (GT 0). It is obvious that the peaks are sharp and their Figure 3. FTIR spectra of pure PMMA polymer (GT 0). It is obvious that the peaks are sharp and their intensity is high. intensity is high. 1900 1400 900PDF Image | Green Chemistry Fabricate Small Band Gap Polymers
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