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Materials 2021, 14, 1786 Materials 2021, 14, 1786 9 of 20 9 of 19 Figure 3. (a) Complete coordination environment for Tb1 center in the crystal structure of TbCP2, Figure 3. (a) Complete coordination environment for Tb1 center in the crystal structure of TbCP2, {[Tb(Haip)(aip)(H2O)2]·H2O}n, with the atoms of the asu drawn in the ball-and-stick model and {[Tb(Haip)(aip)(H2O)2]·H2O}n, with the atoms of the asu drawn in the ball-and-stick model and those those generated by symmetry shown in the stick model (for clarity, most of the H-atoms were generated by symmetry shown in the stick model (for clarity, most of the H-atoms were omitted). (b) omitted). (b) Polyhedral representation of the Tb3+ coordination geometry center. (c) Partial ex- Polyhedral representation of the Tb3+ coordination geometry center. (c) Partial extended structure of tended structure of the TbCP2. Symmetry transformations used to generate equivalent atoms: (i) t−hxe,−Tyb+1C,P−z2;.(Siiy)mx,my−e1t,rzy;(tiriai)n−sxf+o1r,m−ya,ti−ozn;(sivu)sxe,dy+t1o,gz.enerateequivalentatoms:(i)−x,−y+1,−z;(ii)x, y−1, z; (iii) −x+1, −y, −z; (iv) x, y+1, z. The extended crystalline structure features reveal that the crystallographic independ- 2− − ent aiTpheaenxdteHnadipedocrrgyasntiacllminoelescturulecstubreehafevaetausremsurletvideeanlttahteatlitghaendcrsydsutaelltogtrhaepchoiocridni-depen- 2− − dnaetniotnaiwpithavnadrioHuasiTpb3+ocregnatenrisc(mFiogluerceu3lecsanbdehFaivgueraesSm4uatltSidupenptleamteelnigtarnydMsadtuereiatlo).tIhnecoor- 3+ 3+ dfaicnta,tihoensewlitghanvdasrioinutesrTcobnnecetnttheersT(bFigcuenrete3rcs abnyduFnigduenretaSte4antdSubpidpelenmtateentbarridygMinagterial). 3+ modes, leading to the formation of neutral 2D CPs (coordination layers): extended in the In fact, these ligands interconnect the Tb centers by unidentate and bidentate bridging ab plane of the unit cell (Figure 4a). The layers pack along the [001] direction of the unit modes, leading to the formation of neutral 2D CPs (coordination layers): extended in the cell and small pores in the interlayer space, which is occupied with crystallization water ab plane of the unit cell (Figure 4a). The layers pack along the [001] direction of the unit molecules (Figure 4b). Furthermore, the close packing of individual layers is mediated by cell and small pores in the interlayer space, which is occupied with crystallization water strong and highly directional interlayer O−H···O and N−H···O hydrogen bonds (not molecules (Figure 4b). Furthermore, the close packing of individual layers is mediated shown), ultimately creating 3D supramolecular structures (details about the H-bonds in by strong and highly directional interlayer O−H···O and N−H···O hydrogen bonds (not Table 4). shown), ultimately creating 3D supramolecular structures (details about the H-bonds in Table 4).PDF Image | Green Chemistry with Supercritical CO2 and Enzymes
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