PDF Publication Title:
Text from PDF Page: 011
Materials 2021, 14, 1786 resulted in a CP crystallized in a monoclinic system with the crystal structure solved in the space group P21/c, TbCP3. The introduction of the phen in the crystalline structure also led to a decrease in the dimensionality of the CP, relatively to TbCP2, as previously reported in related CPs [12]. The asu of the crystal structure of TbCP3 comprises a Tb3+ center, a fully deprotonated aip2− ligand, a mono-protonated Haip− ligand, a phen mole- cule and one water molecule (uncoordinated), unequivocally confirming the formula of the 1D coordination compound as {[Tb(Haip)(aip)(phen)]⋅H2O}n (Figure 5 and Figure S5 space group P2 /c, TbCP3. The introduc3t+ion of the phen in the crystalline structure also led 1 identical coordination number of the Tb center (eight) in TbCP1, and the same CP di- to a decrease in the dimensionality of the CP, relatively to TbCP2, as previously reported mensionality (1D). Most probably, these similarities can be related with the identical syn- in related CPs [12]. The asu of the crystal structure of TbCP3 comprises a Tb3+ center, thesis conditions, despite the utilization of the additional co-ligand phen. a fully deprotonated aip2− ligand, a mono-protonated Haip− ligand, a phen molecule The Tb3+ center coordinates to six carboxylate O-atoms from three aip2− ligands (two and one water molecule (uncoordinated), unequivocally confirming the formula of the 1D unidentate and one bidentate chelating coordination modes) and from two Haip− ligands coordination compound as {[Tb(Haip)(aip)(phen)]·H2O}n (Figure 5 and Figure S5 in the (two unidentate modes). The metal coordination sphere is completed by two N-atoms Supplementary Material). Looking at TbCP2 and TbCP3 formulas, it can be verified the from the phen ligand, leading to an eight-coordinated center {TbO6N2} showing a dis- exchange of the two coordinated H2O molecules in TbCP2 for a phen molecule in TbCP3. torted dodecahedral geometry (Figure 5b). The Tb–O bond lengths range from 2.277(4) to 11 of 20 in the Supplementary Material). Looking at TbCP2 and TbCP3 formulas, it can be verified The attempt to further decrease the CP water content by using the co-ligand phen the exchange of the two coordinated H2O molecules in TbCP2 for a phen molecule in resulted in a CP crystallized in a monoclinic system with the crystal structure solved in the TbCP3. Interestingly, despite the introduction of the phen ligand, the TbCP3 revealed the Interestingly, despite the introduction of the phen ligand, the TbCP3 revealed the identical 2.453(4) Å, while Tb–N distances are considerably longer, 2.563(5) and 2.598(5) Å. The coordination number of the Tb3+ center (eight) in TbCP1, and the same CP dimensionality O(N)–Tb–O(N) angles are found between 63.51(16)° and 147.31(13)° (for additional details (1D). Most probably, these similarities can be related with the identical synthesis conditions, about these bond lengths and angles, please consult the Supplementary Material, Table despite the utilization of the additional co-ligand phen. S4). FiFgiugruere5. (5a.) Com(ap)letCeoTmbp1lceoteordTinb1atiocnoocrednitneartinontheccernytsetral isntrutchtuerecoryfsTtablCPs3tr,ucture of TbCP3, {[Tb(Haip)(aip)(phen)]·H2O}n, showing the labelling scheme for all the atoms of the first coordina- {[Tb(Haip)(aip)(phen)]·H2O}n, showing the labelling scheme for all the atoms of the first coordination tion sphere (atoms of the asu are drawn in the ball-and-stick model and those generated by sym- sphere (atoms of the asu are drawn in the ball-and-stick model and those generated by symmetry metry are shown in the stick model. H-atoms bonded to carbons were omitted for clarity). (b) Pol- are shown in the stick model. H-atoms bonded to carbons were omitted for clarity). (b) Polyhedral yhedral representation of the Tb3+ coordination geometry center. Symmetry transformations used representation of the Tb3+ coordination geometry center. Symmetry transformations used to generate to generate equivalent atoms: (i) −x,−y+1,−z+1; (ii) −x+1, −y+1 −z+1; (iii) x+1, y, z. equivalent atoms: (i) −x,−y+1,−z+1; (ii) −x+1, −y+1 −z+1; (iii) x+1, y, z. The Tb3+ center coordinates to six carboxylate O-atoms from three aip2− ligands (two unidentate and one bidentate chelating coordination modes) and from two Haip− ligands (two unidentate modes). The metal coordination sphere is completed by two N-atoms from the phen ligand, leading to an eight-coordinated center {TbO6N2} showing a distorted dodecahedral geometry (Figure 5b). The Tb–O bond lengths range from 2.277(4) to 2.453(4) Å, while Tb–N distances are considerably longer, 2.563(5) and 2.598(5) Å. The O(N)–Tb–O(N) angles are found between 63.51(16)◦ and 147.31(13)◦ (for additional details about these bond lengths and angles, please consult the Supplementary Material, Table S4).PDF Image | Green Chemistry with Supercritical CO2 and Enzymes
PDF Search Title:
Green Chemistry with Supercritical CO2 and EnzymesOriginal File Name Searched:
materials-14-01786.pdfDIY PDF Search: Google It | Yahoo | Bing
NFT (Non Fungible Token): Buy our tech, design, development or system NFT and become part of our tech NFT network... More Info
IT XR Project Redstone NFT Available for Sale: NFT for high tech turbine design with one part 3D printed counter-rotating energy turbine. Be part of the future with this NFT. Can be bought and sold but only one design NFT exists. Royalties go to the developer (Infinity) to keep enhancing design and applications... More Info
Infinity Turbine IT XR Project Redstone Design: NFT for sale... NFT for high tech turbine design with one part 3D printed counter-rotating energy turbine. Includes all rights to this turbine design, including license for Fluid Handling Block I and II for the turbine assembly and housing. The NFT includes the blueprints (cad/cam), revenue streams, and all future development of the IT XR Project Redstone... More Info
Infinity Turbine ROT Radial Outflow Turbine 24 Design and Worldwide Rights: NFT for sale... NFT for the ROT 24 energy turbine. Be part of the future with this NFT. This design can be bought and sold but only one design NFT exists. You may manufacture the unit, or get the revenues from its sale from Infinity Turbine. Royalties go to the developer (Infinity) to keep enhancing design and applications... More Info
Infinity Supercritical CO2 10 Liter Extractor Design and Worldwide Rights: The Infinity Supercritical 10L CO2 extractor is for botanical oil extraction, which is rich in terpenes and can produce shelf ready full spectrum oil. With over 5 years of development, this industry leader mature extractor machine has been sold since 2015 and is part of many profitable businesses. The process can also be used for electrowinning, e-waste recycling, and lithium battery recycling, gold mining electronic wastes, precious metals. CO2 can also be used in a reverse fuel cell with nafion to make a gas-to-liquids fuel, such as methanol, ethanol and butanol or ethylene. Supercritical CO2 has also been used for treating nafion to make it more effective catalyst. This NFT is for the purchase of worldwide rights which includes the design. More Info
NFT (Non Fungible Token): Buy our tech, design, development or system NFT and become part of our tech NFT network... More Info
Infinity Turbine Products: Special for this month, any plans are $10,000 for complete Cad/Cam blueprints. License is for one build. Try before you buy a production license. May pay by Bitcoin or other Crypto. Products Page... More Info
| CONTACT TEL: 608-238-6001 Email: greg@infinityturbine.com | RSS | AMP |