Green Chemistry with Supercritical CO2 and Enzymes

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Green Chemistry with Supercritical CO2 and Enzymes ( green-chemistry-with-supercritical-co2-and-enzymes )

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MaMteraitaelrsia2l0s210,214,,1147,816786 1414ofo1f920 points to the residual presence of some additional crystalline phase or compound. Most non-reacted TbCl3 salt, since the EDX spectra of all the CPs reveal the occurrence of probably, these additional peaks can correspond to some residual non-reacted TbCl3 salt, Chloride. since the EDX spectra of all the CPs reveal the occurrence of Chloride. (a) (b) (c) (d) Figure 8. Powder X-ray diffraction (XRD) patterns the all the CP materials obtained experimentally and compared with Figure 8. Powder X-ray diffraction (XRD) patterns the all the CP materials obtained experimentally and compared with the the respective diffractogram obtained by simulation from the single-crystal XRD data: SmCP1 (a), TbCP1 (b), TbCP2 (c) respective diffractogram obtained by simulation from the single-crystal XRD data: SmCP1 (a), TbCP1 (b), TbCP2 (c) and and TbCP3 (d). TbCP3 (d). As expected, the TbCP2 and TbCP3 reveal distinct crystalline morphology and par- As expected, the TbCP2 and TbCP3 reveal distinct crystalline morphology and parti- ticle size (Figure 7c,d, respectively). While the coordination layer material (2D CP TbCP2) cle size (Figure 7c,d, respectively). While the coordination layer material (2D CP TbCP2) shows large plate shape particles, the coordination chain material (1D CP TbCP3) com- shows large plate shape particles, the coordination chain material (1D CP TbCP3) com- prises crystalline particles more elongated and with size variability. The powder XRD prises crystalline particles more elongated and with size variability. The powder XRD analysis of these CPs confirms that the bulk materials were isolated as a pure crystalline analysis of these CPs confirms that the bulk materials were isolated as a pure crystalline phase, since the experimental powder XRD patterns corresponds to the respective pat- phase, since the experimental powder XRD patterns corresponds to the respective patterns terns simulated from the single-crystal data (Figure 8). All the EDX spectra unequivocally simulated from the single-crystal data (Figure 8). All the EDX spectra unequivocally con- confirm incidence of the main elements of the CPs, namely Tb, C and O. In fact, the choice firm incidence of the main elements of the CPs, namely Tb, C and O. In fact, the choice of the synthetic methods is an important factor for the control of size and morphology of of the synthetic methods is an important factor for the control of size and morphology of the CP particles, which is also a fundamental issue regarding the potential applicability of the CP particles, which is also a fundamental issue regarding the potential applicability the materials. Most of the previous discussion based in SEM/EDX and powder XRD is of the materials. Most of the previous discussion based in SEM/EDX and powder XRD is supported by the FT-IR spectra (Figure S6 in Supplementary Material). supported by the FT-IR spectra (Figure S6 in Supplementary Material).

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