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Materials 2021, 14, 1786 18 of 20 References Data Availability Statement: CIF files have been deposited with the Cambridge Crystallographic Data Centre as supplementary publication numbers CCDC-2064873 (SmCP1), CCDC-2064876 (TbCP1), CCDC-2064875 (TbCP2) and CCDC-2064874 (TbCP3). Copies of these data can be obtained online, https://www.ccdc.cam.ac.uk/structures/. Remaining data utilized and shown in this research publication are available upon request directly to the authors. Acknowledgments: L.C.-S. and A.M.G.S. thank FCT/MCTES for the researcher positions obtained in the Individual Call to Scientific Employment Stimulus (Ref. CEECIND/00793/2018) and program DL 57/2016—Norma transitória, respectively. Authors are grateful to the CEMUP—Centro de Materiais da Universidade do Porto, for the technical support for the acquisition of SEM images and EDX spectra of the materials, and the IFIMUP—Instituto de Física de Materiais Avançados, Nanotecnologia e Fotónica da Universidade do Porto, for the assistance in the acquisition of the PXRD patterns. Conflicts of Interest: The authors declare no conflict of interest. 1. Bunzli, J.C.G.; Eliseeva, S.V. Intriguing aspects of lanthanide luminescence. Chem. Sci. 2013, 4, 1939–1949. [CrossRef] 2. Utochnikova, V.V.; Kuzmina, N.P. Photoluminescence of lanthanide aromatic carboxylates. Russ. J. Coord. Chem. 2016, 42, 679–694. [CrossRef] 3. Heine, J.; Müller-Buschbaum, K. Engineering metal-based luminescence in coordination polymers and metal–organic frameworks. Chem. Soc. Rev. 2013, 42, 9232–9242. [CrossRef] 4. Einkauf, J.D.; Clark, J.M.; Paulive, A.; Tanner, G.P.; de Lill, D.T. A general model of sensitized luminescence in lanthanide-based coordination polymers and metal–organic framework materials. Inorg. Chem. 2017, 56, 5544–5552. [CrossRef] [PubMed] 5. Gorai, T.; Schmitt, W.; Gunnlaugsson, T. Highlights of the development and application of luminescent lanthanide based coordination polymers, MOFs and functional nanomaterials. Dalton Trans. 2021, 50, 770–784. [CrossRef] [PubMed] 6. Li, S.; Li, X.; Jiang, Y.; Hou, Z.; Cheng, Z.; Ma, P.; Li, C.; Lin, J. Highly luminescent lanthanide fluoride nanoparticles functionalized by aromatic carboxylate acids. RSC Adv. 2014, 4, 55100–55107. [CrossRef] 7. Yang, L.; Zhang, S.; Qu, X.; Yang, Q.; Liu, X.; Wei, Q.; Xie, G.; Chen, S. Synthesis, crystal structure and photoluminescence property of Eu/Tb MOFs with mixed polycarboxylate ligands. J. Solid State Chem. 2015, 231, 223–229. [CrossRef] 8. Zhou, W.; Wu, Y.-P.; Zhou, Z.-H.; Qin, Z.-S.; Ye, X.; Tian, F.-Y.; Li, D.-S. Construction of a series of lanthanide metal–organic frameworks (Ln-MOFs) based on a new symmetrical penta-aromatic carboxylate strut: Structure, luminescent and magnetic properties. Inorg. Chim. Acta 2016, 453, 757–763. [CrossRef] 9. Chen, Q.; Cheng, J.; Wang, J.; Li, L.; Liu, Z.; Zhou, X.; You, Y.; Huang, W. A fluorescent Eu(III) MOF for highly selective and sensitive sensing of picric acid. Sci. China Chem. 2019, 62, 205–211. [CrossRef] 10. Yang, G.L.; Jiang, X.L.; Xu, H.; Zhao, B. Applications of MOFs as luminescent sensors for environmental pollutants. Small 2021, 202005327. [CrossRef] 11. Jin, J.; Xue, J.J.; Liu, Y.C.; Yang, G.P.; Wang, Y.Y. Recent progresses in luminescent metal-organic frameworks (LMOFs) as sensors for the detection of anions and cations in aqueous solution. Dalton Trans. 2021, 50, 1950–1972. [CrossRef] 12. D’Vries, R.F.; Gomez, G.E.; Hodak, J.H.; Soler-Illia, G.J.A.A.; Ellena, J. Tuning the structure, dimensionality and luminescent properties of lanthanide metal-organic frameworks under ancillary ligand influence. Dalton Trans. 2016, 45, 646–656. [CrossRef] [PubMed] 13. Luo, L.L.; Qu, X.L.; Li, Z.; Li, X.; Sun, H.L. Isostructural lanthanide-based metal-organic frameworks: Structure, photolumines- cence and magnetic properties. Dalton Trans. 2017, 47, 925–934. [CrossRef] [PubMed] 14. Zheng, K.; Liu, Z.Q.; Huang, Y.; Chen, F.; Zeng, C.H.; Zhong, S.; Ng, S.W. Highly luminescent Ln-MOFs based on 1,3- adamantanediacetic acid as bifunctional sensor. Sens. Actuators B Chem. 2018, 257, 705–713. [CrossRef] 15. Xu, Q.-W.; Dong, G.; Cui, R.; Li, X. 3D lanthanide-coordination frameworks constructed by a ternary mixed-ligand: Crystal structure, luminescence and luminescence sensing. CrystEngComm 2020, 22, 740–750. [CrossRef] 16. Liu, J.; Hang, M.; Wu, D.; Jin, J.; Cheng, J.-G.; Yang, G.; Wang, Y.-Y. Fine-tuning the porosities of the entangled isostructural Zn(II)-based metal–organic frameworks with active sites by introducing different N-auxiliary ligands: Selective gas sorption and efficient CO2 conversion. Inorg. Chem. 2020, 59, 2450–2457. [CrossRef] [PubMed] 17. Kariem, M.; Kumar, M.; Yawer, M.; Sheikh, H.N. Solvothermal synthesis and structure of coordination polymers of Nd(III) and Dy(III) with rigid isophthalic acid derivatives and flexible adipic acid. J. Mol. Struct. 2017, 1150, 438–446. [CrossRef] 18. Chandran, P.S.; Mol, U.S.; Drisya, R.; Sudarsanakumar, M.R.; Kurup, M.P. Structural studies of poly[(μ2-acetato)(μ3-5- aminoisophthalato)diaquacerium(III) monohydrate]: A new three dimensional fluorescent metal-organic framework constructed from dimers of CeO9 polyhedra with hydrophilic ‘S’ shaped channels. J. Mol. Struct. 2017, 1137, 396–402. [CrossRef] 19. Winkless, L.; Tan, R.H.C.; Zheng, Y.; Motevalli, M.; Wyatt, P.B.; Gillin, W.P. Quenching of Er(III) luminescence by ligand C–H vibrations: Implications for the use of erbium complexes in telecommunications. Appl. Phys. Lett. 2006, 89, 111115. [CrossRef] 20. Bischof, C.; Wahsner, J.; Scholten, J.; Trosien, S.; Seitz, M. Quantification of C−H quenching in near-IR luminescent Ytterbium and Neodymium cryptates. J. Am. Chem. Soc. 2010, 132, 14334–14335. [CrossRef] [PubMed]PDF Image | Green Chemistry with Supercritical CO2 and Enzymes
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