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Energies 2019, 12, 809 Catalyst Reactor Type Pt/H-ZSM-5 Batch Pt/USY Batch ZSM-5-Zn-20 Continuous Mo-Zn/Al2 O3 Batch Ni/Al2 O3 Continuous Ni–Cu/Al2 O3 Continuous Ni–Mo/Al2 O3 Batch Co–Mo/Al2 O3 Batch Ni–W/Al2 O3 Batch Ni–Mo/Al2 O3 Batch Ni–Mo/B2 O3 -Al2 O3 Batch Ru/SiO2 Continuous Ru/Al13-montmorillonite Continuous Ru/H-Y Continuous HZSM-5 Batch Sulfated Zr2O3 Batch Ni–Mo/B2 O3 -Al2 O3 Batch Ni–Mo/B2 O3 -Al2 O3 Batch Ni/Al2 O3 Continuous Ni–Cu/Al2 O3 Continuous Ni–Cu/Al2 O3 Continuous Ni–Mo/Al2 O3 Continuous Oil Jatropha Jatropha Camelina Carinata Hemp seed 3 Hemp seed 3 WCO 4 WCO 4 WCO 4 WCO 4 WCO 4 WCO 4 WCO 4 WCO 4 WCO 4 WCO 4 LTG 5 STG 6 H2/Oil T (◦C) Ratio n.a. 270 n.a. 270 n.a. 500 n.a. 350 300 350 300 350 666 300 666 300 666 300 666 350 666 350 400 350 400 350 400 350 n.a. 400–420 n.a. 400–420 666 350 666 350 2400 375 2400 375 2400 375 250 350 P (bar) Table 5. Cont. LHSV Duration Conversion (h−1) (h) % Selectivity among Oil Product (wt%) 78.9 (C15–C18) 68.15 (C15–C18) 52.39 (C13–C15) 83 (C12–C18) 90% (C10–C17) 100 (C10–C20) 93 (C15–C18) 84.7 (C15–C18) 92.8 (C15–C18) 90.7 (C15–C18) 87.1 (C15–C18) 98.9 (C11–C20) 89.8 (C11–C20) 56.5 (C11–C20) 30.55-36.3 (Gas oil) 41.18-44.61 (Gas oil) 92.1 (C15–C18) 86.6 (C15–C18) - 92% (Diesel) 94% (Diesel) 86.11 (C15–C18) 14 of 41 Main Products 1 Ref. C15–C18 (C17/C18 = 0.40) 93 C15–C18 (C17/C18 = 0.51) 93 C13–C15 and also C7–C8 25.09 wt% 111 C12–C18 112 C10–C17 (C17 equal to 49–62 wt%) 101 wt%YG7 C15–C18 (iSH/nSH 1 = 2.6/96) 80 C15–C18 (iSH/nSH 1 = 3.4/94.8) 80 Gas products and unconverted liquids 101 Diesel (34wt% C17) 101 Diesel (74 wt% C17) 101 C15–C18 (C17/C18 = 0.47) 73 75 75 wt%YG 7 75 wt%YG7 Lard 65 n.a. 65 n.a. 1 0.6 21–58 n.a. 40 4.7 40 4.7 70 2.8 70 2.8 70 2.8 70 2.8 70 2.8 20 15.2 20 15.2 20 15.2 10 n.a. 10 n.a. 70 2.8 70 2.8 40 2 40 2 40 2 45 0.8 12 100 12 31.2 n.a. 76.8 n.a. >92 n.a. 100 n.a. 100 3 99.6 3 99.3 3 100 3 99.8 3 99.9 n.a. n.a. n.a. 100 n.a. n.a. 1 n.a. 1 n.a. 3 99.8 3 99.3 3 inadequate 3 100 8 100 n.a. n.a. C10–C17 (C17 equal to 80 wt%) C15–C18 (iSH/nSH 1 = 1.4/97.5) C15–C18 (iSH/nSH 1 = 6.4/89.7) C15–C18 (iSH/nSH 1 = 2.2/97.3) C15–C18 (iSH/nSH 1 = 3.8/94.8) C15–C18 (iSH/nSH 1 = 7.5/91.4) C11–C20 (iSH/nSH 1 = 0.08) C11–C20 and 9.1 wt% C5–C10 (iSH/nSH C11–C20 and 42.8 wt% C5–C10 (iSH/nSH 101 80 80 80 80 80 106 1 = 0.2) 106 1 = 0.43) 106 also 15.57–16.76% gasoline and 9.99–11.83% kerozene 113 also 10.04–14.68% gasoline and 6.51–10.32% kerozene 113 1 nSH = normal Saturated Hydrocarbons, iSH=isomer (branched) Saturated Hydrocarbons; 2 FCC hydrocracking microactivity test unit; 3 25% hemp seed oil dissolved on dodecane; 4 WCO =Waste Cooking Oil; 5 LTG = Liquid Trap Grease; 6 STG = Solid Trap Grease; 7 75 wt% Yellow Grease in dodecane.PDF Image | Green Diesel: Biomass Feedstocks, Production Technologies
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