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Green Pathway Utilizing CO2 Cycloaddition Reaction Epoxide

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Green Pathway Utilizing CO2 Cycloaddition Reaction Epoxide ( green-pathway-utilizing-co2-cycloaddition-reaction-epoxide )

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Processes 2020, 8, 548 19 of 22 Acknowledgments: Financial support provided by the Thailand Research Fund (TRF) and Office of the Higher Education Commission (grant no. MRG6180262), and King Mongkut’s Institute of Technology Ladkrabang, KMITL (grant no. KREF046209) is gratefully acknowledged. W. Kiatkittipong and S. Assabumrungrat would also like to acknowledge the support from the “Research Chair Grant” National Science and Technology Development Agency (NSTDA). The authors thank Peerawat Wongsurakul for his assistance. Conflicts of Interest: The authors declare no conflict of interest. References 1. Liu, L.; Wang, S.M.; Han, Z.B.; Ding, M.; Yuan, D.Q.; Jiang, H.L. Exceptionally Robust In-Based Metal-Organic Framework for Highly Efficient Carbon Dioxide Capture and Conversion. Inorg. Chem. 2016, 55, 3558–3565. [CrossRef] [PubMed] 2. Bals, C.; Bellmann, E.; Bode, A.; Edenhofer, O.; Fischedick, M.; Gaertner, L.-E.; Gerling, P.; Helseth, J.M.; Kühn, M.; Liebscher, A. CCU and CCS–Building Blocks for Climate Protection in Industry. Analysis, Options and Recommendations; Utzverlag GmbH: München, Germany, 2019. 3. Zhang, Z.; Pan, S.Y.; Li, H.; Cai, J.; Olabi, A.G.; Anthony, E.J.; Manovic, V. Recent advances in carbon dioxide utilization. Renew. Sustain. Energy Rev. 2020, 125, 109799. [CrossRef] 4. Liang, S.; Liu, H.; Jiang, T.; Song, J.; Yang, G.; Han, B. Highly efficient synthesis of cyclic carbonates from CO2 and epoxides over cellulose/KI. Chem. Commun. 2011, 47, 2131–2133. [CrossRef] 5. Ng, C.K.; Toh, R.W.; Lin, T.T.; Luo, H.K.; Hor, T.S.A.; Wu, J. Metal-salen molecular cages as efficient and recyclable heterogeneous catalysts for cycloaddition of CO2 with epoxides under ambient conditions. Chem. Sci. 2019, 10, 1549–1554. [CrossRef] 6. Lu, B.B.; Yang, J.; Liu, Y.Y.; Ma, J.F. A Polyoxovanadate-Resorcin[4]arene-Based Porous Metal-Organic Framework as an Efficient Multifunctional Catalyst for the Cycloaddition of CO2 with Epoxides and the Selective Oxidation of Sulfides. Inorg. Chem. 2017, 56, 11710–11720. [CrossRef] [PubMed] 7. Styring, P.; Jansen, D.; de Coninck, H.; Reith, H.; Armstrong, K. Carbon Capture and Utilisation in the Green Economy; Centre for Low Carbon Futures: New York, NY, USA, 2011. 8. Aresta, M. Carbon dioxide utilization: Chemical, biological and technological applications. In Greenhouse Gases: Mitigation and Utilization, Proceedings of the CHEMRAWN-XVII and ICCDU-IX Conference, Kingston, ON, Canada, 8–12 July 2007; Queen’s University: Kingston, ON, Canada, 2009; pp. 123–149. 9. Liu, Q.; Wu, L.; Jackstell, R.; Beller, M. Using carbon dioxide as a building block in organic synthesis. Nat. Commun. 2015, 6, 1–15. [CrossRef] 10. Luo, J.; Preciado, S.; Xie, P.; Larrosa, I. Carboxylation of Phenols with CO2 at Atmospheric Pressure. Chem. Eur. J. 2016, 22, 6798–6802. [CrossRef] 11. Wendling, T.; Risto, E.; Krause, T.; Gooßen, L.J. Salt-Free Strategy for the Insertion of CO2 into C−H Bonds: Catalytic Hydroxymethylation of Alkynes. Chem. Eur. J. 2018, 24, 6019–6024. [CrossRef] 12. Zou, B.; Hu, C. Synthesis of Cyclic Carbonates from Alkenyl and Alkynyl Substrates. Chin. J. Chem. 2017, 35, 541–550. [CrossRef] 13. Dabral, S.; Schaub, T. The Use of Carbon Dioxide (CO2) as a Building Block in Organic Synthesis from an Industrial Perspective. Adv. Synth. Catal. 2019, 361, 223–246. [CrossRef] 14. Wang, L.; Zhang, G.; Kodama, K.; Hirose, T. An efficient metal- and solvent-free organocatalytic system for chemical fixation of CO2 into cyclic carbonates under mild conditions. Green Chem. 2016, 18, 1229–1233. [CrossRef] 15. Jadhav, A.H.; Thorat, G.M.; Lee, K.; Lim, A.C.; Kang, H.; Seo, J.G. Effect of anion type of imidazolium based polymer supported ionic liquids on the solvent free synthesis of cycloaddition of CO2 into epoxide. Catal. Today 2016, 265, 56–67. [CrossRef] 16. North, M. Synthesis of Cyclic Carbonates from Carbon Dioxide and Epoxides; Elsevier: Amsterdam, The Netherlands, 2013; ISBN 9780444538826. 17. Bobadilla, L.F.; Lima, S.; Urakawa, A. Cycloaddition of CO2 and Epoxides over Reusable Solid Catalysts. Adv. Catal. Mater. 2015, 271–312. [CrossRef] 18. Shaikh, R.R.; Pornpraprom, S.; D’Elia, V. Catalytic Strategies for the Cycloaddition of Pure, Diluted, and Waste CO2 to Epoxides under Ambient Conditions. ACS Catal. 2018, 8, 419–450. [CrossRef] 19. Gruttadauria, M.; Giacalone, F. Catalytic Methods in Asymmetric Synthesis: Advanced Materials, Techniques, and Applications; John Wiley & Sons: Hoboken, NJ, USA, 2011; ISBN 9780470641361.

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