PDF Publication Title:
Text from PDF Page: 004
Inorganics 2017, 5, 25 Inorganics 2017, 5, 25 Inorganics 2017, 5, 25 4 of 17 4 of 17 4 of 17 Figure 3. Molecular scheme of mixed chelators with different architectures, which belong to the class Figure 3. Molecular scheme of mixed chelators with different architectures, which belong to the class of of bio-reagents. (a) chelators formed by a single or dual reagents, i.e. carboxylic acids; (b) mixed Figure 3. Molecular scheme of mixed chelators with different architectures, which belong to the class bio-reagents. (a) chelators formed by a single or dual reagents, i.e. carboxylic acids; (b) mixed chelators chelators including several bio-reagents with complex structure. of bio-reagents. (a) chelators formed by a single or dual reagents, i.e. carboxylic acids; (b) mixed including several bio-reagents with complex structure. chelators including several bio-reagents with complex structure. Figure 4 shows the X-ray diffraction (XRD) patterns for the MnO2 nanowires prepared by the reduction of KMnO4 by a carboxylic acid at 350 °C. Using ascorbic acid (vitamin C) as a single chelator, Figure 4 shows the X-ray diffraction (XRD) patterns for the MnO2 nanowires prepared by the Figure 4 shows the X-ray diffraction (XRD) patterns for the MnO2 nanowires prepared by the the product crystallizes in the tetragonal struc◦ture of the α-MnO2 cryptomelane (space group I4/m) reduction of KMnO by a carboxylic acid at 350 C. Using ascorbic acid (vitamin C) as a single chelator, reduction of KMn4O4 by a carboxylic acid at 350 °C. Using ascorbic acid (vitamin C) as a single chelator, with a 2 × 2 tunnels. The mean crystallite size of the α-MnO2 nanoneedles is Lc = 14 nm [13]. The same theproductcrystallizesinthetetragonalstructureoftheα-MnO cryptomelane(spacegroupI4/m) the product crystallizes in the tetragonal structure of the α-MnO22cryptomelane (space group I4/m) material prepared by a green technique using a mixed chelator composed by bio-reagents such as withwait2h×a22×tu2ntunnenlse.lsT.hTehmemeaenancrcyrystsatallliltietessizizeeoffttheα-MnO2 naannoonneeeddlelsesisisLcL=1=41n4mnm[13[]1.3T]h.eTshaemseame 2c those that exhibit a smaller crystallite size of 6.4 nm, which results in primary nanorods of ~17 nm in matmeraiatelrpiarelparerepdarbeydabygraeegnretenchtneciqhuneiquseinugsiangmaixmedixcehdeclahteolratcoormcopmospeodsebdybyiob-rieoa-rgeeangtesnstuscshucahsathsose diameter and 84 nm in length. Slight modifications of the synthesis recipe induce different those that exhibit a smaller crystallite size of 6.4 nm, which results in primary nanorods of ~17 nm in that exhibit a smaller crystallite size of 6.4 nm, which results in primary nanorods of ~17 nm in diameter morphologies of nanostructured α-MnO2; for instance, sea-urchin-like shape, with a diameter of ~3 μm, diameter and 84 nm in length. Slight modifications of the synthesis recipe induce different and 84 nm in length. Slight modifications of the synthesis recipe induce different morphologies of were prepared in acidic conditions [13], while a neutral medium provided a caddice-clew-like MnO2 morphologies of nanostructured α-MnO2; for instance, sea-urchin-like shape, with a diameter of ~3 μm, nanostructured α-MnO ; for instance, sea-urchin-like shape, with a diameter of ~3 μm, were prepared showing lower electr2ochemical performance [14]. The use of mixed chelator has been successful for were prepared in acidic conditions [13], while a neutral medium provided a caddice-clew-like MnO2 inactihdeicgcronwdthitiofnsL[i1-r3i]c,hwehlailyeearendeucotrmalpmouendisu.mThperoLvii[dLei0d.2Nai0c.2aMddn0i.c6]eO-c2leowxi-dliekewMasnOprepsharoewdinbgylaower 2 showing lower electrochemical performance [14]. The use of mixed chelator has been successful for electcromchbienmediccailtrpicerafcoidrm(CaAn)cean[d14a]n. Tetheyluesnedoifamiinxedtetcrhaaeclaetiocrahciads(bEeDeTnAs)urcocuetses.fTuylpfiocraltlyh,eCgAroawndth of the growth of Li-riche layered compounds. The Li[Li0.2Ni0.2Mn0.6]O2 oxide was prepared by a EDTA dissolved in NH4OH was added to a solution containing requested stoichiometry of metal Li-riche layered compounds. The Li[Li0.2Ni0.2Mn0.6]O2 oxide was prepared by a combined citric acid combined citric acid (CA) and an ethylenediamine tetraacetic acid (EDTA) route. Typically, CA and acetate. The viscous gel was formed at ~120 °C and the final product heated at 850 °C for few hours. (CA) and an ethylenediamine tetraacetic acid (EDTA) route. Typically, CA and EDTA dissolved in EDTA dissolved in NH4OH was added to a solution containing requested stoichiometry of metal Note the crucial importance of the acid/metal ratio, which in the present case is 1.5:1:1 to keep the NH4OH was added to a solution containing requested stoichiometry of metal acetate. The viscous acetate. The viscous gel was formed at ~120 °C and the final product heated at 850 °C for few hours. nanostructure [15]. ◦ gel was formed at ~120 C and the final product heated at 850 ◦ C for few hours. Note the crucial Note the crucial importance of the acid/metal ratio, which in the present case is 1.5:1:1 to keep the importance of the acid/metal ratio, which in the present case is 1.5:1:1 to keep the nanostructure [15]. nanostructure [15]. Figure 4. XRD patterns for (a) α-MnO2 nanoneedles prepared by the reduction of KMnO4 using the single ascorbic-acid route and (b) α-MnO2 nanowires prepared using the mixed chelator shown in Figure 34b. .XCRoDpypraitgthertnpserfomris(asi)oαn-fMronmO2Spnrainogneer.edles prepared by the reduction of KMnO4 using the Figure 4. XRD patterns for (a) α-MnO2 nanoneedles prepared by the reduction of KMnO4 using the single ascorbic-acid route and (b) α-MnO2 nanowires prepared using the mixed chelator shown in single ascorbic-acid route and (b) α-MnO2 nanowires prepared using the mixed chelator shown in Figure 3b. Copyright permission from Springer. Figure 3b. Copyright permission from Springer.PDF Image | Nanotechnology of Positive Electrodes for Li-Ion Batteries
PDF Search Title:
Nanotechnology of Positive Electrodes for Li-Ion BatteriesOriginal File Name Searched:
inorganics-05-00025.pdfDIY PDF Search: Google It | Yahoo | Bing
NFT (Non Fungible Token): Buy our tech, design, development or system NFT and become part of our tech NFT network... More Info
IT XR Project Redstone NFT Available for Sale: NFT for high tech turbine design with one part 3D printed counter-rotating energy turbine. Be part of the future with this NFT. Can be bought and sold but only one design NFT exists. Royalties go to the developer (Infinity) to keep enhancing design and applications... More Info
Infinity Turbine IT XR Project Redstone Design: NFT for sale... NFT for high tech turbine design with one part 3D printed counter-rotating energy turbine. Includes all rights to this turbine design, including license for Fluid Handling Block I and II for the turbine assembly and housing. The NFT includes the blueprints (cad/cam), revenue streams, and all future development of the IT XR Project Redstone... More Info
Infinity Turbine ROT Radial Outflow Turbine 24 Design and Worldwide Rights: NFT for sale... NFT for the ROT 24 energy turbine. Be part of the future with this NFT. This design can be bought and sold but only one design NFT exists. You may manufacture the unit, or get the revenues from its sale from Infinity Turbine. Royalties go to the developer (Infinity) to keep enhancing design and applications... More Info
Infinity Supercritical CO2 10 Liter Extractor Design and Worldwide Rights: The Infinity Supercritical 10L CO2 extractor is for botanical oil extraction, which is rich in terpenes and can produce shelf ready full spectrum oil. With over 5 years of development, this industry leader mature extractor machine has been sold since 2015 and is part of many profitable businesses. The process can also be used for electrowinning, e-waste recycling, and lithium battery recycling, gold mining electronic wastes, precious metals. CO2 can also be used in a reverse fuel cell with nafion to make a gas-to-liquids fuel, such as methanol, ethanol and butanol or ethylene. Supercritical CO2 has also been used for treating nafion to make it more effective catalyst. This NFT is for the purchase of worldwide rights which includes the design. More Info
NFT (Non Fungible Token): Buy our tech, design, development or system NFT and become part of our tech NFT network... More Info
Infinity Turbine Products: Special for this month, any plans are $10,000 for complete Cad/Cam blueprints. License is for one build. Try before you buy a production license. May pay by Bitcoin or other Crypto. Products Page... More Info
CONTACT TEL: 608-238-6001 Email: greg@infinityturbine.com (Standard Web Page)