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184 Chapter 4 Stoichiometry of Chemical Reactions 2KI(aq) + Pb(NO3)2(aq) ⟶ PbI2(s) + 2KNO3(aq) This observation is consistent with the solubility guidelines: The only insoluble compound among all those involved is lead iodide, one of the exceptions to the general solubility of iodide salts. The net ionic equation representing this reaction is: Pb2+(aq) + 2I−(aq) ⟶ PbI2(s) Lead iodide is a bright yellow solid that was formerly used as an artist’s pigment known as iodine yellow (Figure 4.4). The properties of pure PbI2 crystals make them useful for fabrication of X-ray and gamma ray detectors. Figure 4.4 A precipitate of PbI2 forms when solutions containing Pb2+ and I− are mixed. (credit: Der Kreole/ Wikimedia Commons) The solubility guidelines in Table 4.2 may be used to predict whether a precipitation reaction will occur when solutions of soluble ionic compounds are mixed together. One merely needs to identify all the ions present in the solution and then consider if possible cation/anion pairing could result in an insoluble compound. For example, mixing solutions of silver nitrate and sodium fluoride will yield a solution containing Ag+, NO3 − , Na+, and F− ions. Aside from the two ionic compounds originally present in the solutions, AgNO3 and NaF, two additional ionic compounds may be derived from this collection of ions: NaNO3 and AgF. The solubility guidelines indicate all nitrate salts are soluble but that AgF is one of the exceptions to the general solubility of fluoride salts. A precipitation reaction, therefore, is predicted to occur, as described by the following equations: NaF(aq) + AgNO3(aq) ⟶ AgF(s) + NaNO3(aq) (molecular) Ag+(aq) + F−(aq) ⟶ AgF(s) (net ionic) Example 4.3 Predicting Precipitation Reactions This content is available for free at http://cnx.org/content/col11760/1.9PDF Image | Stoichiometry of Chemical Reactions
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