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Stoichiometry of Chemical Reactions

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Stoichiometry of Chemical Reactions ( stoichiometry-chemical-reactions )

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Chapter 4 Stoichiometry of Chemical Reactions 201 Figure 4.11 Airbags deploy upon impact to minimize serious injuries to passengers. (credit: Jon Seidman) 4.4 Reaction Yields By the end of this section, you will be able to: • Explain the concepts of theoretical yield and limiting reactants/reagents. • Derive the theoretical yield for a reaction under specified conditions. • Calculate the percent yield for a reaction. The relative amounts of reactants and products represented in a balanced chemical equation are often referred to as stoichiometric amounts. All the exercises of the preceding module involved stoichiometric amounts of reactants. For example, when calculating the amount of product generated from a given amount of reactant, it was assumed that any other reactants required were available in stoichiometric amounts (or greater). In this module, more realistic situations are considered, in which reactants are not present in stoichiometric amounts. Limiting Reactant Consider another food analogy, making grilled cheese sandwiches (Figure 4.12): 1 slice of cheese + 2 slices of bread ⟶ 1 sandwich Stoichiometric amounts of sandwich ingredients for this recipe are bread and cheese slices in a 2:1 ratio. Provided with 28 slices of bread and 11 slices of cheese, one may prepare 11 sandwiches per the provided recipe, using all the provided cheese and having six slices of bread left over. In this scenario, the number of sandwiches prepared has been limited by the number of cheese slices, and the bread slices have been provided in excess.

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