Bipolar Membrane Electrodialysis for LiOH Production

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Bipolar Membrane Electrodialysis for LiOH Production ( bipolar-membrane-electrodialysis-lioh-production )

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polar membranes was designed and constructed. The stack was constructed from PTFE, Membranes 2021, 11, 575 with an effective membrane area of 27.5 cm2 (55 mm × 50 mm). The design was a “filter press” type where membranes and separators could be configured according to different flow compartments (see Figure 3). The separators were made of EPDM, with a thickness of 1.6 mm. consisting of a HCl compartment, an anion-exchange membrane, a LiCl compartment, a cation-exchange membrane, and a LiOH compartment. These were stacked between two The electrodialysis stack’s repetitive unit corresponded to a three-compartment cell, bipolar membranes. In this way, the stack could be configured with several three-com- 2.5. Bipolar Membrane Electrodialysis System partment cells, among which different electrolytes were distributed. The stack was fed 2.5.1. Stack Design and Construction with five flow streams corresponding to LiCl, LiOH, HCl, and two electrode solution 8 of 29 To perform experimental tests on LiOH production, an electrodialysis stack with streams. The main feed to the stack was the LiCl solution, from which lithium ions mi- bipolar membranes was designed and constructed. The stack was constructed from PTFE, grated into the LiOH solution and chloride2ions migrated into the HCl stream. As the withaneffectivemembraneareaof27.5cm (55mm×50mm).Thedesignwasa“filter electrode solution, 0.5 M Na2SO4 was used; its purpose was to provide conductivity in the press” type where membranes and separators could be configured according to different electrode compartment, and simultaneously prevent chlorine gas (Cl2) formation in the flow compartments (see Figure 3). The separators were made of EPDM, with a thickness of anode compartment. 1.6 mm. Figure 3. LiOH production by bipolar membrane electrodialysis; configuration of two three- Figure 3. LiOH production by bipolar membrane electrodialysis; configuration of two three-com- compartment cells. BP: Bipolar membrane, AM: Anion exchange membrane, CM: Cation exchange partment cells. BP: Bipolar membrane, AM: Anion exchange membrane, CM: Cation exchange membrane. membrane. The electrodialysis stack’s repetitive unit corresponded to a three-compartment cell, 2.5.2. LiOH Production Experimental Tests Using BMED consisting of a HCl compartment, an anion-exchange membrane, a LiCl compartment, To test the LiOH production range, six long-running tests were performed. The a cation-exchange membrane, and a LiOH compartment. These were stacked between system was configured in batch mode, recirculating different feed solutions and two bipolar membranes. In this way, the stack could be configured with several three- measuring concentration variation over time (see Figure 4). compartment cells, among which different electrolytes were distributed. The stack was Flow rate in each compartment was set between 1.0 and 1.5 cm∙s−1 using peristaltic fed with five flow streams corresponding to LiCl, LiOH, HCl, and two electrode solution pumps (Watson-Marlow 520SN/R2, Falmouth, UK), and a DC power supply (GW Instek streams. The main feed to the stack was the LiCl solution, from which lithium ions GPR-1810HD, New Taipei, Taiwan) was used to set the electric current. migrated into the LiOH solution and chloride ions migrated into the HCl stream. As the electrode solution, 0.5 M Na2SO4 was used; its purpose was to provide conductivity in the electrode compartment, and simultaneously prevent chlorine gas (Cl2) formation in the anode compartment. 2.5.2. LiOH Production Experimental Tests Using BMED To test the LiOH production range, six long-running tests were performed. The system was configured in batch mode, recirculating different feed solutions and measuring concentration variation over time (see Figure 4).

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