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Bipolar Membrane Electrodialysis for LiOH Production

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Bipolar Membrane Electrodialysis for LiOH Production ( bipolar-membrane-electrodialysis-lioh-production )

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Membranes 2021, 11, 575 12 of 29 concentration difference on both sides of the membrane. Thus, high LiCl concentrations promote diffusive transport of lithium ions, whose effect on total transport decreases at higher current densities. A problem observed when applying the Hittorf method at high concentrations was Membranes 2021, 11, x FOR PEER REVIEW 12 of 30 that when working with a 20-mL LiOH sample volume, the sensitivity of calculating molar flux and lithium-ion transport number increased due to the low final volume and high concentration, according to Equations (1) and (2). Figure 5. Lithium transport number in cation-exchange membranes according to LiOH concentration and current density Figure 5. Lithium transport number in cation-exchange membranes according to LiOH concentration and current density (14 wt% LiCl): (a) CMX membrane; (b) CMB membrane. (14 wt% LiCl): (a) CMX membrane; (b) CMB membrane. 3.2.1. Influence of Current Density Current density shows influence on lithium transport. As can be seen in Figure 5, the lithium transport number decreases at higher current densities. This can be best observed for initial concentrations of 0.5 wt% and 2.5 wt% LiOH. In the CMX membrane, comparing LiOH concentrations at 0.5 wt% and 2.5 wt%, it was observed that when increasing cur-

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