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Electro-Driven Materials and Processes for Lithium

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Electro-Driven Materials and Processes for Lithium ( electro-driven-materials-and-processes-lithium )

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Membranes 2022, 12, 343 12 of 27 3.2. Capacitive Deionization (CDI) Capacitive Deionization is an electro-adsorption technique developed in the late 1970s for the removal of ions from aqueous solutions by electrosorption on porous material [90,91]. CDI has been primarily applied to seawater and brackish water desalination, sewage remediation, as well as in the softening of drinking water [92,93]. 3.2.1. Operation of CDI Systems Electro-active adsorbent materials, such as those used in CDI, mostly involve ph- ysisorption at the solid–liquid interface to support ultra-selective extraction of resources [90,92,94–96]. Typical CDI configurations are shown in Figure 4. The most popular material for CDI electrodes is activated carbon (AC) due to its low cost, high electrical conductivity, and large specific surface area. However, AC does not exhibit any selectivity toward ions due to the absence of selective sites (Figure 5a). To generate Li+ ion selectivity, the surface of activated carbon could be modified by selective moieties such as α-MnO2 [96].

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