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Lithium recovery synthetic geothermal brine electrodialysis

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Lithium recovery synthetic geothermal brine electrodialysis ( lithium-recovery-synthetic-geothermal-brine-electrodialysis )

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International Seminar on Mineral and Coal Technology IOP Publishing IOP Conf. Series: Earth and Environmental Science 882 (2021) 012003 doi:10.1088/1755-1315/882/1/012003 on the side of the feed stream. Meanwhile, the recovery solution was flowed on the concentrate side to carry the lithium ions that escaped due to the difference in electric potential. The parameters to be measured were the solution flux. In the second experiment, the geothermal brine temperature was changed until it reached the desired temperature variation. (30ยฐC and 40ยฐC) and ran like the first try. In the second experiment, the used electric voltage was 4V because this condition was the optimum condition based on the previous first experiment. 3. Mathematical Models The research was based on a review of the mass transfer theory in membranes in the electrodialysis (ED) process. As shown in Figure 3, the mass transfer mechanism that occurs is as follows, 1. Mass transfer of lithium ions towards the membrane surface on the feed side 2. The mass transfer of lithium ions from the feed side of the solution towards the concentrate side is due to the potential difference. 3. Transfer of lithium ions from the membrane surface of the concentrate side to the recovery solution. Figure 3. Electrodialysis Mechanism [27]. Where Co represents the ion concentration in bulk and Cm represents the ion concentration in the layer near the membrane. In the ED system, the flux equation as a function of time can be formulated as in Equation 1 [25]: Where, ๐ฝ๐‘  ๐ด ๐‘‰ ๐‘กโ€ฒ = ion flux = effective membrane surface area = volume of solution = time 4. Results and discussion 4.1. Voltage variation ๐ฝ๐‘  = ๐‘‰ (1) ๐ด.๐‘กโ€ฒ The first research was conducted in various operating conditions where 2V and 4V varied the voltage. The study was performed at an operating temperature of 40ยฐC so that the experimental results were obtained Figure 4. The study was conducted using crossflow and co-current flow. The flux in the membrane expresses the amount of permeate that can be passed by the membrane per unit area and per unit time. Flux is often used as an indicator of membrane performance quality. 5

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