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Lithium recovery synthetic geothermal brine electrodialysis

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Lithium recovery synthetic geothermal brine electrodialysis ( lithium-recovery-synthetic-geothermal-brine-electrodialysis )

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International Seminar on Mineral and Coal Technology IOP Publishing IOP Conf. Series: Earth and Environmental Science 882 (2021) 012003 doi:10.1088/1755-1315/882/1/012003 molecules move; the more lithium ions move to the concentrate side. Vice versa, at a lower operating temperature, the lithium recovery rate is also slower. Besides that, the membrane's pores will enlarge at higher temperatures so that more solution escapes [13]. So based on the solution flux from each temperature variation, it can be concluded that the best condition in the first study was at an operating temperature of 40°C because it produced the largest solution flux compared to other lower temperature conditions. 5. Conclusions This research shows that temperature and potential difference are essential parameters in separating lithium from brine, such as synthetic geothermal brine, used during this research. The increase in feed temperature and the potential difference in the ED system increased the resulting permeate flux. Based on the results of experiments that have been carried out with two types of independent variables, namely temperature and electric voltage, it can be concluded that the optimum operating conditions during the experiment are at a temperature of 40°C and using a voltage of 4V. This phenomenon shows that the increase in feed temperature in the electrodialysis system increases the resulting permeate flux. The molecules in the solution move faster at higher temperatures. Also, based on experimental results and theoretically, it is shown that an increase in the electric voltage in the ED system increases the resulting permeate flux because the higher the voltage, the greater the electricity delivered and the faster the redox reaction that occurs in the system. References [1] Glasstone S and Sesonske A 1994 Nuclear reactor engineering: Reactor systems engineering (Boston, MA: Springer US) [2] Opitz A, Badami P, Shen L, Vignarooban K and Kannan A M 2017 Can Li-Ion batteries be the panacea for automotive applications? Renew. Sustain. Energy Rev. 68 685–92 [3] Murodjon S, Yu X, Li M, Duo J and Deng T 2020 Lithium recovery from brines including seawater, salt lake brine, underground water and geothermal water Thermodynamics and Energy Engineering ed P Vizureanu (IntechOpen) p 90371 [4] Flexer V, Baspineiro C F and Galli C I 2018 Lithium recovery from brines: A vital raw material for green energies with a potential environmental impact in its mining and processing Sci. Total Environ. 639 1188–204 [5] Ji Z-Y, Yang F-J, Zhao Y-Y, Liu J, Wang N and Yuan J-S 2017 Preparation of titanium-base lithium ionic sieve with sodium persulfate as eluent and its performance Chem. Eng. J. 328 768–75 [6] Bundschuh J and Tomaszewska B 2017 Geothermal water management (London: CRC Press) [7] Siekierka A, Tomaszewska B and Bryjak M 2018 Lithium capturing from geothermal water by hybrid capacitive deionization Desalination 436 8–14 [8] Tomaszewska B and Szczepański A 2014 Possibilities for the efficient utilisation of spent geothermal waters Environ. Sci. Pollut. Res. 21 11409–17 [9] Mulder M 1996 Basic Principles of Membrane Technology (Dordrecht: Springer Netherlands) [10] Nie X-Y, Sun S-Y, Sun Z, Song X and Yu J-G 2017 Ion-fractionation of lithium ions from magnesium ions by electrodialysis using monovalent selective ion-exchange membranes Desalination 403 128–35 [11] Zhang Y, Wang L, Sun W, Hu Y and Tang H 2020 Membrane technologies for Li+/Mg2+ separation from salt-lake brines and seawater: A comprehensive review J. Ind. Eng. Chem. 81 7–23 [12] Bunani S, Yoshizuka K, Nishihama S, Arda M and Kabay N 2017 Application of bipolar membrane electrodialysis (BMED) for simultaneous separation and recovery of boron and lithium from aqueous solutions Desalination 424 37–44 [13] Zhao L-M, Chen Q-B, Ji Z-Y, Liu J, Zhao Y-Y, Guo X-F and Yuan J-S 2018 Separating and recovering lithium from brines using selective-electrodialysis: Sensitivity to temperature 7

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