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P507 TBP Carriers for Lithium Extraction from Brines

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P507 TBP Carriers for Lithium Extraction from Brines ( p507-tbp-carriers-lithium-extraction-from-brines )

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Membranes 2022, 12, 839 12 of 13 20. Almeida, M.I.G.S.; Cattrall, R.W.; Kolev, S.D. Recent trends in extraction and transport of metal ions using polymer inclusion membranes (PIMs). J. Membr. Sci. 2012, 415–416, 9–23. [CrossRef] 21. Nghiem, L.D.; Mornane, P.; Potter, I.D.; Perera, J.M.; Cattrall, R.W.; Kolev, S.D. Extraction and transport of metal ions and small organic compounds using polymer inclusion membranes (PIMs). J. Membr. Sci. 2006, 281, 7–41. [CrossRef] 22. Pereira, N.; John, A.S.; Cattrall, R.W.; Perera, J.M.; Kolev, S.D. Influence of the composition of polymer inclusion membranes on their homogeneity and flexibility. Desalination 2009, 236, 327–333. [CrossRef] 23. Bahrami, S.; Yaftian, M.R.; Najvak, P.; Dolatyari, L.; Shayani-Jam, H.; Kolev, S.D. PVDF-HFP based polymer inclusion membranes containing Cyphos® IL 101 and aliquat® 336 for the removal of Cr(VI) from sulfate solutions. Sep. Purif. Technol. 2020, 250, 117251. [CrossRef] 24. Radzyminska-Lenarcik, E.; Maslowska, K.; Urbaniak, W. Removal of copper (II), zinc (II), cobalt (II), and nickel (II) ions by PIMs doped 2-alkylimidazoles. Membranes 2022, 12, 16. [CrossRef] [PubMed] 25. Bonggotgetsakul, Y.Y.; Cattrall, R.W.; Kolev, S.D. Extraction of gold(III) from hydrochloric acid solutions with a PVC-based polymer inclusion membrane (PIM) containing cyphos® IL 104. Membranes 2015, 5, 903–914. [CrossRef] 26. Pospiech, B. Hydrometallurgical recovery of cobalt (II) from acidic chloride solutions by transport through polymer inclusion membranes. Physicochem. Probl. Miner. Processing 2013, 49, 641–649. 27. Pospiech, B. Selective recovery of cobalt (II) towards lithium (I) from chloride media by transport across polymer inclusion membrane with triisooctylamine. Pol. J. Chem. Technol. 2014, 16, 15–20. [CrossRef] 28. Wang, L.; Paimin, R.; Cattrall, R.W.; Shen, W.; Kolev, S.D. The extraction of cadmium(II) and copper(II) from hydrochloric acid solutions using an Aliquat 336/PVC membrane. J. Membr. Sci. 2000, 176, 105–111. [CrossRef] 29. Kolev, S.D.; Baba, Y.; Cattrall, R.W.; Tasaki, T.; Pereira, N.; Perera, J.M.; Stevens, G.W. Solid phase extraction of zinc(II) using a PVC-based polymer inclusion membrane with di(2-ethylhexyl)phosphoric acid (D2EHPA) as the carrier. Talanta 2009, 78, 795–799. [CrossRef] 30. Bahrami, S.; Dolatyari, L.; Shayani-Jam, H.; Yaftian, M.R.; Kolev, S.D. On the potential of a poly(vinylidenefluoride-co- hexafluoropropylene) polymer inclusion membrane containing aliquat® 336 and dibutyl phthalate for V(V) extraction from sulfate solutions. Membranes 2022, 12, 90. [CrossRef] 31. Cai, C.; Yang, F.; Zhao, Z.; Liao, Q.; Bai, R.; Guo, W.; Chen, P.; Zhang, Y.; Zhang, H. Promising transport and high-selective separation of Li(I) from Na(I) and K(I) by a functional polymer inclusion membrane (PIM) system. J. Membr. Sci. 2019, 579, 1–10. [CrossRef] 32. Paredes, C.; Miguel, E.R.D.S. Selective lithium extraction and concentration from diluted alkaline aqueous media by a polymer inclusion membrane and application to seawater. Desalination 2020, 487, 114500. [CrossRef] 33. Zhang, C.; Mu, Y.; Zhao, S.; Zhang, W.; Wang, Y. Lithium extraction from synthetic brine with high Mg2+/Li+ ratio using the polymer inclusion membrane. Desalination 2020, 496, 114710. [CrossRef] 34. Xu, L.; Zeng, X.; He, Q.; Deng, T.; Zhang, C.; Zhang, W. Stable ionic liquid-based polymer inclusion membranes for lithium and magnesium separation. Sep. Purif. Technol. 2022, 288, 120626. [CrossRef] 35. Su, H.; Li, Z.; Zhang, J.; Liu, W.; Zhu, Z.; Wang, L.; Qi, T. Combining selective extraction and easy stripping of lithium using a ternary synergistic solvent extraction system through regulation of Fe3+ coordination. ACS Sustain. Chem. Eng. 2020, 8, 1971–1979. [CrossRef] 36. Kozlowski, C.A.; Walkowiak, W. Removal of chromium(VI) from aqueous solutions by polymer inclusion membranes. Water Res. 2002, 36, 4870–4876. [CrossRef] 37. Zioui, D.; Arous, O.; Mameri, N.; Kerdjoudj, H.; Sebastian, M.S.; Vilas, J.L.; Nunes-Pereira, J.; Lanceros-Méndez, S. Membranes based on polymer miscibility for selective transport and separation of metallic ions. J. Hazard. Mater. 2017, 336, 188–194. [CrossRef] 38. Azizitorghabeh, A.; Rashchi, F.; Babakhani, A. Stoichiometry and structural studies of Fe(III) and Zn(II) solvent extraction using D2EHPA/TBP. Sep. Purif. Technol. 2016, 171, 197–205. [CrossRef] 39. Liu, C.; Chen, L.; Chen, J.; Zou, D.; Deng, Y.; Li, D. Application of P507 and isooctanol extraction system in recovery of scandium from simulated red mud leach solution. J. Rare Earths 2019, 37, 1002–1008. [CrossRef] 40. Binks, B.P.; Isa, L.; Tyowua, A.T.J.L. Direct measurement of contact angles of silica particles in relation to double inversion of pickering emulsions. Langmuir 2013, 29, 4923–4927. [CrossRef] 41. An, J.W.; Kang, D.J.; Tran, K.T.; Kim, M.J.; Lim, T.; Tran, T. Recovery of lithium from uyuni salar brine. Hydrometallurgy 2012, 117–118, 64–70. [CrossRef] 42. Sun, S.-Y.; Cai, L.-J.; Nie, X.-Y.; Song, X.; Yu, J.-G. Separation of magnesium and lithium from brine using a desal nanofiltration membrane. J. Water Process Eng. 2015, 7, 210–217. [CrossRef] 43. Zhao, Y.; Xiang, X.; Wang, M.; Wang, H.; Li, Y.; Li, J.; Yang, H. Preparation of LiOH through BMED process from lithium-containing solutions: Effects of coexisting ions and competition between Na+ and Li+. Desalination 2021, 512, 115126. [CrossRef] 44. Kagaya, S.; Ryokan, Y.; Cattrall, R.W.; Kolev, S.D. Stability studies of poly(vinyl chloride)-based polymer inclusion membranes containing Aliquat 336 as a carrier. Sep. Purif. Technol. 2012, 101, 69–75. [CrossRef]

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One project is converting salt (brine) based water conditioners to simultaneously produce power.

In addition, there are many opportunities to extract Lithium from brine (salt lakes, groundwater, and producer water).

Salt water or brine are huge sources for lithium. Most of the worlds lithium is acquired from a brine source. It's even in seawater in a low concentration. Brine is also a byproduct of huge powerplants, which can now use that as an electrolyte and a huge flow battery (which allows storage at the source).

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