Patent Lithium Extraction with coated ion exchange particles

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Patent Lithium Extraction with coated ion exchange particles ( patent-lithium-extraction-with-coated-ion-exchange-particles )

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US 10,695,694B2 9 10 Li,MOZ(M=Ti,Mn,Sn),LiMn2012,LiTis012,LiMn204, 40nm,lesthanabout50nm,lesthanabout60nm,les Li_.6Mn604,LIMO,(M=A1,Cu,Ti),Li,V04,Li,Si,O, thanabout70nm,lesthanabout80nm,lesthanabout90 Li,CuP207, Al(OH)3, LiCl.xAl(OH)3.yH2O, nm,lesthanabout10nm,lesthanabout1,0nm,les SnO2.xSb2O.yH,O,TiO2.xSbOs.yH,O,solidsolutions thanabout10,0nm,lesthanabout10,0nm,more thereof,orcombinationsthereof.Insomeembodiment,xis 5 thanabout10nm,morethanabout20nm,morethanabout selectedfrom0.1,0.2,0.3,0.4,0.5,0.6,0.7,0.8,0.9,1,2, 30nm,morethanabout40nm,morethanabout50nm, 3,4,5,6,7,8,9,and10.Insomeembodiments,yisselected morethanabout60nm,morethanabout70nm,morethan from0.1,0.2,0.3,0.4,0.5,0.6,0.7,0.8,0.9,1,2,3,4,5,6, about80nm,morethanabout90nm,morethanabout10 Xand 7,8,9,and10.Insomeembodiments, ?isindepen nm,morethanabout1,0nm,morethanabout10,0nm, dentlyselectedfrom0.1,0.2,0.3,0.4,0.5,0.6,0.7,0.8,0.9,10fromabout1nm toabout10,0nm,fromabout1nmto 1,2,3,4,5,6,7,8,9,and10.Insomeembodiments,anion about1,0nm,fromabout1nmtoabout10nm,from exchangematerialcomprisesLiFePO4,Li,SnOz,LiMn03, about1nmtoabout80nm,fromabout1nmtoabout60nm, LizTiO3,Li,Ti,012,Li,Mn,012,Li,Mn604,solidsolu fromabout1nmtoabout40nm,orfromabout1nmto tionsthereof,orcombinationsthereof. about20nm. Insomeembodiments,theionexchangematerialissyn-15 Insomeembodiments,thecoatedionexchangeparticle thesizedbyamethodsuchashydrothermal,solvothermal, hasanaveragediameteroflesthanabout10um,lesthan sol-gel,solidstate,moltensaltflux,ionexchange,micro about20um,lesthanabout30um,lesthanabout40um, wave,balmiling,chemicalprecipitation,co-precipitation, lesthanabout50um,lesthanabout60um,lesthanabout vapordeposition,orcombinationsthereof.Insomeembodi 70um,lesthanabout80um,lesthanabout90um,les ments,theionexchangematerialisynthesizedbyamethod20thanabout10um,lesthanabout1,0um,lesthanabout suchaschemicalprecipitation,hydrothermal,solidstate, 10,0um,lesthanabout10,0um,morethanabout10 microwave,orcombinationsthereof. um,morethanabout20um,morethanabout30um,more Insomeembodiments,theionexchangematerialsare thanabout40um,morethanabout50um,morethanabout synthesizedinalithiatedstatewithasub-laticefulyor 60um,morethanabout70um,morethanabout80um, partlyocupiedbylithiumions.Insomeembodiments,the25morethanabout90um,morethanabout10um,morethan ionexchangematerialsaresynthesizedinahydratedstate about1,0um,morethanabout10,0um,fromabout1 withasub-laticefulyorpartlyocupiedbyhydrogenions. umtoabout10,0um,fromabout1umtoabout1,0um, Insomeembodiments,theionexchangematerialandthe fromabout1umtoabout10um,fromabout1umtoabout coatingmaterialformoneormoreconcentrationgradients 80um,fromabout1umtoabout60um,fromabout1um wherethechemicalcompositionofthecoatedionexchange30toabout40um,orfromabout1umtoabout20um.Insome particlevariesbetwentwoormorecompositions.Insome embodiments,thecoatedionexchangeparticleshavean embodiments,thechemicalcompositionvariesbetwenthe averagesizeoflesthanabout10um,lesthanabout1,0 ionexchangematerialsandthecoatinginamannerthatis um,orlesthanabout10,0um.Insomeembodiments,the continuous,discontinuous,orcontinuousanddiscontinuous coatedionexchangeparticlesaresecondaryparticlescom indiferentregionsofthecoatedionexchangeparticle.In35prisedofsmalerprimaryparticles,whereinthesecondary someembodiments,theionexchangematerialsandthe particleshaveanaveragediameteroflesthanabout10um, coatingmaterialsformaconcentrationgradientthatextends lesthanabout20um,lesthanabout30um,lesthanabout overathicknesoflesthan1nm,lesthan10nm,lesthan 40um,lesthanabout50um,lesthanabout60um,les 10nm,lesthan1,0nm,lesthan10,0nm,lesthan thanabout70um,lesthanabout80um,lesthanabout90 10,0nm,morethan1nm,morethan10nm,morethan40um,lesthanabout10um,lesthanabout1,0um,les 10nm,morethan1,0nm,morethan10,0nm,from thanabout10,0um,lesthanabout10,0um,more about1nmtoabout100,000nm,fromabout10nmtoabout thanabout10um,morethanabout20um,morethanabout 10,0nm,orfrom about10toabout1,0nm. 30um,morethanabout40um,morethanabout50um, ParticleSizeofCoatedIonExchangeParticle morethanabout60um,morethanabout70um,morethan Insomeembodiments,thecoatedionexchangeparticle45about80um,morethanabout90um,morethanabout10 hasanaveragediameteroflesthanabout10nm,lesthan um,morethanabout1,0um,morethanabout10,0um, about20nm,lesthanabout30nm,lesthanabout40nm, fromabout1umtoabout10,0um,fromabout1umto lesthanabout50nm,lesthanabout60nm,lesthanabout about1,0um,fromabout1umtoabout10um,from 70nm,lesthanabout80nm,lesthanabout90nm,les about1umtoabout80um,fromabout1umtoabout60um, thanabout10nm,lesthanabout1,0nm,lesthanabout 50 from about1um toabout40um,orfrom about1um to 10,0nm,lesthanabout10,0nm,morethanabout10 about20um. nm,morethanabout20nm,morethanabout30nm,more Inanembodiment,theaveragediameterofthecoatedion thanabout40nm,morethanabout50nm,morethanabout exchangeparticlesortheaveragediameterofcoatedion 60nm,morethanabout70nm,morethanabout80nm, exchangeparticleswhicharesecondaryparticlescomprised morethanabout90nm,morethanabout10nm,morethan5ofsmalerprimaryparticles,isdeterminedbymeasuringthe about1,0nm,morethanabout10,0nm,fromabout1 particlesizedistributionofthecoatedionexchangeparticles nmtoabout10,0nm,fromabout1nmtoabout1,0nm, orthecoatedionexchangeparticleswhicharesecondary fromabout1nmtoabout10nm,fromabout1nmtoabout particlescomprisedofsmalerprimaryparticles,anddeter 80nm,fromabout1nmtoabout60nm,fromabout1nm miningthemeanparticlesize. toabout40nm,orfromabout1nmtoabout20nm.Insome60 Insomeembodiments,coatedionexchangeparticles embodiments,thecoatedionexchangeparticleshavean comprisecoatingonprimaryionexchangeparticlesor averagesizeoflesthanabout10nm,lesthanabout1,0 secondaryionexchangeparticles.Insomeembodiments, nm,orlesthanabout10,0nm.Insomeembodiments,the coatedionexchangeparticlescomprisethecoatingon coatedionexchangeparticlesaresecondaryparticlescom primaryionexchangeparticlesandsecondaryionexchange prisedofsmalerprimaryparticles,whereinthesecondary 65particles.Insomeembodiments,thesecondaryionexchange particleshaveanaveragediameteroflesthanabout10nm, particlescompriseprimaryionexchangeparticles.Insome lesthanabout20nm,lesthanabout30nm,lesthanabout embodiments,thecoatingisontheprimaryionexchange

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