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Recovering Lithium Chloride From a Geothermal Brine 1984

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Recovering Lithium Chloride From a Geothermal Brine 1984 ( recovering-lithium-chloride-from-geothermal-brine-1984 )

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RECOVERING LITHIUM CHLCi'RIDE FROM A GEOTHERMAL BRINE By L. E. Schultze1 and D. J. Bauer2 ABSTRACT The Bureau of Mines has devised techniques to recover lithium from geothermal brines as the chloride. More than 99 pct of the lithium was precipitated from a brine containing 170 mg/L Li by adding a solution of AICl3 and increasing the pH to 7.5 with lime slurry. The Li-Al precipi- tate was dissolved in HCl and sparged with gaseous HCI to recover the AlCl3 ; this resulted in a solution containing LiCl and CaCI2 • The solu- tion was evaporated at 1000 C to obtain a mixture of the chlorides from which 97 pct of the lithium was recovered and 90 pct of the calcium was rejected by leaching with tetrahydrofuran. The LiCl recovered by evap- oration of the tetrahydrofuran was purified by dissolution in water and treatment'with oxalic acid. The final LiClsolution contained 89 pct of the lithium originally present in the brine and had a purity of 99.9 pet. Research chemist. 2supervisory chemical engineer. Reno Research Center, Bureau of Mines, Reno, NV.

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