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Recovering Lithium Chloride From a Geothermal Brine 1984

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Recovering Lithium Chloride From a Geothermal Brine 1984 ( recovering-lithium-chloride-from-geothermal-brine-1984 )

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4 +- 80 0 a. Z 0 60 t= ~ a.. 40 (3 w a:: a.. 20 0 Temperature, 75° C 2 AI:Li MOLE RATIO used for lime precipitation was employed to precipitate lithium (fig. 4). Lime slurry was added to the first train of four 90-g~l reactors~ and conditions de- veloped during lime precipitation studies were used. The precipitated hydroxides and silica were thickened and removed by filtration in a 1- by I-ft filter press. After 24 h of operation, lithium precip- itation in the second train of four 90- gal reactors was begun by treating the FIGURE 2. - Effect of AI:Li ratios on lithium precipitation. 100 +- 80 o a. ~ 60 i= ~ a.. fd a:: a.. Conditions: AI:Li mole ratio, 4.0 Temperature, 75° C Bulk metals hydroxides Li-AI filler cake 2 0 ~~----~----~~----~------~----~ pH FIGURE 3. - Effect of pH on precipitation of lithium with aluminum hydroxide. Injection RESULTS AND DISCUSSION PRECIPITATION was an aging effect. When an aged, pre- treated brine was used in lithium pre- A contract study outlined conditions cipitation tests, a decrease in lithium for precipitation of lithium with aqueous recovery was observed. In one test using AlCl3 (9). Data from the study showed brine treated with lime 5 months before the effect of Al:Li ratio on precipita- lithium precipitation, recovery was 56 tion of lithium at pH 7.5 (fig. 2) and pet. When the brine was pretreated with the effect of pH at an Al:Li mole ratio of 4 (fig. 3). The data for both figures were obtained at 75° C. More than 95 pet of the lithium was precipitated when the Al:Li mole ratio was at least 2.5 and at pH of 6 to 8. Bench-scale tests verified that these conditions precipitated at least 95 pet of the lithium from the brine. lime within a few days of lithium precip- itation, more than 95 pet of the lithium was precipitated. The causes of aging were not investigated because the lithium recovery flow scheme employed lime pre- treatment immediately before lithium pre- cipitation and aging was not a factor. A large-scale lithium precipitation test was carried out during the opera- tion of the MRU for lime precipitation of An interesting phenomenon encountered during the preliminary bench-scale tests Fe, Mn, Pb, and Zn (6). The equipment Postflash brine FIGURE 4. - Flowsheet for lithium precipitation.

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Recovering Lithium Chloride From a Geothermal Brine 1984

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