Recovery of Lithium from Geothermal Water

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Recovery of Lithium from Geothermal Water ( recovery-lithium-from-geothermal-water )

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Daoud, Yokohama, Yoshizuka Li concentration in geothermal water is about a hundred fold higher than that in seawater. But, the reasonable recovery technique of Li has not been developed. The purpose of this project study is to learn basic chemistry required to develop a new technique in future for recovery of Li from geothermal water. 4. Experimental 4.1 Materials The geothermal water sample used in this report comes from Obama binary power plant located in Obama, Unzen, Nagasaki Prefecture, Japan. Led by Koyo Denki Co., Ltd. The properties of the geothermal water samples used are listed in Table 1 Table 1: Reported physico-chemistry geothermal water samples (averaged concentration) Parameters Value Concentration (mg/L) pH 8,53 EC (mS/ cm) 1.475 TDS (g/l) - Salinity - B( mg/L) 14.7 Cations Li + Na+ K+ NH4+ Ca2+ Mg2+ Concentration (mg/L) Anions 5.2 HCO3- 2540 F- 259 Cl- 17 NO3- 194 SO4- 212 217 0.5 4590 - 379 The polymer iron sulfate solution of chemical formula FeSO4・7H2O of molar mass 278.01 g/mol was used to remove silicic acid before recovery experiment of lithium. For Li extraction, λ-MnO2 was used as an adsorbent of Li. λ-MnO2 adsorbent in granulated form was produced and supplied from The University of Kitakyushu, Japan. The preparation procedure is the same as that mentioned in the literature. [Yoshizuka and Nalan Kabay 2018]. The properties of λ-MnO2 adsorbent are summarized in Table 2. Table 2. Properties of λ-MnO2 adsorbent. Type Spinel Form granulated Specific surface area, m2/g Mean particle size, mm 1.4 Total lithium capacity, mg Li/g -* 1.0 – 5.0 Other reagents used in this study were of analytical reagent grade. All of the solutions were prepared with ultrapure water.

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Recovery of Lithium from Geothermal Water

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In addition, there are many opportunities to extract Lithium from brine (salt lakes, groundwater, and producer water).

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