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Recovery of Lithium from Geothermal Water

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Recovery of Lithium from Geothermal Water ( recovery-lithium-from-geothermal-water )

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4.2 Methods of the final column experiment for recovery of Li 4.2.1 Removal of silica acid is filtered using an qualitative filter paper (110mm Size). Li extraction 4.2.3 Extraction of Li: adsorption by column experiment Finally, the mixture Daoud, Yokohama, Yoshizuka In this experiment, the volume of the samples to be analyzed is 10 L, 200 ml of polymer iron sulfate solution is required. Then mix 10 L geothermal water with 200 ml of polymer iron sulfate solution. The pH of the mixture drops around 1 to 2 so we control the pH, by adding 4 mol/L or 1 mol/L NaOH to bring the pH around 8 or 9. We leave 1h for the reagents to react well. A co-precipitation deposit of silica and iron hydroxide is obtained. The resulting filtrate will be used for Fill glass wool with 9.27 g of λ-Mno2 adsorbent then the column is treated with 1.0 Mol of hydrochloric acid for a period of 2 h. then washed for 1 h with deionized water. This is an ion exchange reaction (Yoshizuka 2018). As shown in the equation 1 Li +type λ-MnO2 is transformed to H+ type λ-MnO2. The exchange of ions occurs only between the lithium ion and the hydrogen ion. Figure 5: Schematic drawing of column experiment Li 1.5Mn2O4 + 1.5H+ H1.5Mn2O4 + 1.5Li+ (1) The adsorption of Li was carried out from 0 L of geothermal water for 6 days and 21 hours (143.8 hours), and then washed 1 L of deionized water, and finally eluted 1.2 L of 1 mol/L HCl. Take 0.6 L of eluent obtained after elution and start the evaporation step. During evaporation, the temperature is adjusted around 90 oC, to obtain 1 mL concentrated liquid, and then dried to obtain the precipitate powder

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Recovery of Lithium from Geothermal Water

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Daoud, Yoshizuka - 2020 - A Study on Recovery of Lithium from Geothermal Water and Study of Assal geothermal field.pdf

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