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Separation of Magnesium and Lithium from Brine Water

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Separation of Magnesium and Lithium from Brine Water ( separation-magnesium-and-lithium-from-brine-water )

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Resources 2022, 11, 89 10 of 12 Figure 8. The XRD pattern of the solid product after the precipitation process from bittern and brine water. Table 4. Phase and Semiquantitative composition of the solid product of brine water after the pre- cipitation process. Phase Diopside (CaMgO6Si2) Li2MgO4SiLi2(MgSiO4) LiMg4Na3O30Si12 Titanite (CaSi2O5) Halite (NaCl) Lithium Chloride (LiCl) Forsterite (Mg2SiO4) Cristobalite (SiO2) Solid Precipitates of (wt%.) Bittern Brine Water 42.7 60.4 10.0 4.1 4.2 - 18.7 12.3 8.7 9.9 - 8.4 2.3 5.0 13.5 - Lithium cannot be extracted from either of these compounds by water leaching; thus, much lithium that enters the solid cannot be recovered. These complex bonds can be made for catalyst raw materials by being processed into hectorite compounds [22]. In the so- dium silicate precipitation process with brine water, fewer complex compounds were pro- duced, namely only Li2MgO4SiLi2(MgSiO4) in the amount of 4.1%. Most of the lithium involved in the precipitation process in brine water is lithium chloride (LiCl) at 8.4%, so the lithium that has settled on the solids resulting from brine water precipitation is recov- ered more easily by the washing process. Regarding the presence of SiO2 in the solid precipitates, there is a possibility of mul- tiple reactions in the formation of calcium silicate to 2CaO.SiO2, 3CaO.SiO2, 4CaO.SiO2 compounds and others [18]. Moreover, it is possible to form free SiO2 gel or silica precip- itates, where this silica gel or silica precipitate plays a role in the binding process of lithium ions in the filtrate. The formation of free silica can be seen from the number of Si elements

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