Advances in Clean Fuel Ethanol Production from CO2 Reduction

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Catalysts 2020, 10, 1287 23 of 25 60. Yang, P.P.; Zhang, X.L.; Gao, F.Y.; Zheng, Y.R.; Niu, Z.Z.; Yu, X.; Liu, R.; Wu, Z.Z.; Qin, S.; Chi, L.P.; et al. Protecting Copper Oxidation State via Intermediate Confinement for Selective CO2 Electroreduction to C2+ Fuels. J. Am. Chem. Soc. 2020, 142, 6400–6408. [CrossRef] [PubMed] 61. Liang, Z.Q.; Zhuang, T.T.; Seifitokaldani, A.; Li, J.; Huang, C.W.; Tan, C.S.; Li, Y.; De Luna, P.; Dinh, C.T.; Hu, Y.; et al. Copper-on-nitride enhances the stable electrosynthesis of multi-carbon products from CO2. Nat. Commun. 2018, 9, 3828. [CrossRef] 62. Chen, C.; Sun, X.; Lu, L.; Yang, D.; Ma, J.; Zhu, Q.; Qian, Q.; Han, B. Efficient electroreduction of CO2 to C2 products over B-doped oxide-derived copper. Green Chem. 2018, 20, 4579–4583. [CrossRef] 63. Zhou, Y.; Che, F.; Liu, M.; Zou, C.; Liang, Z.; De Luna, P.; Yuan, H.; Li, J.; Wang, Z.; Xie, H.; et al. Dopant-induced electron localization drives CO2 reduction to C2 hydrocarbons. Nat. Chem. 2018, 10, 974–980. [CrossRef] 64. Zhuang, T.-T.; Liang, Z.-Q.; Seifitokaldani, A.; Li, Y.; De Luna, P.; Burdyny, T.; Che, F.; Meng, F.; Min, Y.; Quintero-Bermudez, R.; et al. Steering post-C–C coupling selectivity enables high efficiency electroreduction of carbon dioxide to multi-carbon alcohols. Nat. Catal. 2018, 1, 421–428. [CrossRef] 65. Ma, W.; Xie, S.; Liu, T.; Fan, Q.; Ye, J.; Sun, F.; Jiang, Z.; Zhang, Q.; Cheng, J.; Wang, Y. Electrocatalytic reduction of CO2 to ethylene and ethanol through hydrogen-assisted C–C coupling over fluorine-modified copper. Nat. Catal. 2020. [CrossRef] 66. Luo, M.; Wang, Z.; Li, Y.C.; Li, J.; Li, F.; Lum, Y.; Nam, D.H.; Chen, B.; Wicks, J.; Xu, A.; et al. Hydroxide promotes carbon dioxide electroreduction to ethanol on copper via tuning of adsorbed hydrogen. Nat. Commun. 2019, 10, 5814. [CrossRef] 67. Han, Z.; Kortlever, R.; Chen, H.Y.; Peters, J.C.; Agapie, T. CO2 Reduction Selective for C≥2 Products on Polycrystalline Copper with N-Substituted Pyridinium Additives. ACS Cent. Sci. 2017, 3, 853–859. [CrossRef] 68. Thevenon, A.; Rosas-Hernandez, A.; Peters, J.C.; Agapie, T. In-Situ Nanostructuring and Stabilization of Polycrystalline Copper by an Organic Salt Additive Promotes Electrocatalytic CO2 Reduction to Ethylene. Angew. Chem. Int. Ed. 2019, 58, 16952–16958. [CrossRef] 69. Wakerley, D.; Lamaison, S.; Ozanam, F.; Menguy, N.; Mercier, D.; Marcus, P.; Fontecave, M.; Mougel, V. Bio-inspired hydrophobicity promotes CO2 reduction on a Cu surface. Nat. Mater. 2019, 18, 1222–1227. [CrossRef] 70. Li, F.; Li, Y.C.; Wang, Z.; Li, J.; Nam, D.-H.; Lum, Y.; Luo, M.; Wang, X.; Ozden, A.; Hung, S.-F.; et al. Cooperative CO2-to-ethanol conversion via enriched intermediates at molecule–metal catalyst interfaces. Nat. Catal. 2019, 3, 75–82. [CrossRef] 71. Jia, F.; Yu, X.; Zhang, L. Enhanced selectivity for the electrochemical reduction of CO2 to alcohols in aqueous solution with nanostructured Cu–Au alloy as catalyst. J. Power Sources 2014, 252, 85–89. [CrossRef] 72. Ishimaru, S.; Shiratsuchi, R.; Nogami, G. Pulsed Electroreduction of CO2 on Cu-Ag Alloy Electrodes. J. Electrochem. Soc. 2000, 147, 1864. [CrossRef] 73. Hoang, T.T.H.; Verma, S.; Ma, S.; Fister, T.T.; Timoshenko, J.; Frenkel, A.I.; Kenis, P.J.A.; Gewirth, A.A. Nanoporous Copper-Silver Alloys by Additive-Controlled Electrodeposition for the Selective Electroreduction of CO2 to Ethylene and Ethanol. J. Am. Chem. Soc. 2018, 140, 5791–5797. [CrossRef] 74. Dutta, A.; Montiel, I.Z.; Erni, R.; Kiran, K.; Rahaman, M.; Drnec, J.; Broekmann, P. Activation of bimetallic AgCu foam electrocatalysts for ethanol formation from CO2 by selective Cu oxidation/reduction. Nano Energy 2020, 68. [CrossRef] 75. Ma, S.; Sadakiyo, M.; Heima, M.; Luo, R.; Haasch, R.T.; Gold, J.I.; Yamauchi, M.; Kenis, P.J. Electroreduction of Carbon Dioxide to Hydrocarbons Using Bimetallic Cu-Pd Catalysts with Different Mixing Patterns. J. Am. Chem. Soc. 2017, 139, 47–50. [CrossRef] [PubMed] 76. Ren, D.; Gao, J.; Pan, L.; Wang, Z.; Luo, J.; Zakeeruddin, S.M.; Hagfeldt, A.; Grätzel, M. Atomic Layer Deposition of ZnO on CuO Enables Selectiveand Efficient Electroreduction of Carbon Dioxide to Liquid Fuels. Angew. Chem. Int. Ed. 2019, 58, 15036–15040. [CrossRef] 77. Jung, H.; Lee, S.Y.; Lee, C.W.; Cho, M.K.; Won, D.H.; Kim, C.; Oh, H.S.; Min, B.K.; Hwang, Y.J. Electrochemical Fragmentation of Cu2O Nanoparticles Enhancing Selective C-C Coupling from CO2 Reduction Reaction. J. Am. Chem. Soc. 2019, 141, 4624–4633. [CrossRef] 78. Zhao, K.; Liu, Y.; Quan, X.; Chen, S.; Yu, H. CO2 Electroreduction at Low Overpotential on Oxide-Derived Cu/Carbons Fabricated from Metal Organic Framework. ACS Appl. Mater. Interfaces 2017, 9, 5302–5311. [CrossRef]

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