Cell Temperature in Direct Methanol Fuel Cell Operation

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Cell Temperature in Direct Methanol Fuel Cell Operation ( cell-temperature-direct-methanol-fuel-cell-operation )

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Processes 2020, 8, 353 5 of 10 up to 333 K and decreased beyond that due to the dry-out effect in the cell. From the dynamic studies, it is clear that the temperature is the most influencing variable on the output voltage of DMFC. Hence, this working temperature was selected as a manipulated variable for further investigation. Step response analysis was carried out in simulation to validate the developed mathematical model and its behavior. Step input changes were given at the operating temperatures of 313 K, 323 K, and 333 K (25%, 50%, 75% of the cell temperature) with ± 10% and ± 15%. Step response of the system at 25% of the cell temperature for a step change of ± 10%, and a step change of ± 15% of cell temperature were observed and are given in Figure 6. Similar runswere conducted at 50% of the cell temperature and 75% of cell temperature and are recorded in Figures 7 and 8, respectively. From the step response curves, it was concluded that the developed model was behaving linearly in these operating temperatures. Figure 3. Effect of methanol flowrate. Figure 4. Effect of methanol concentration.

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